Urchin-like Co3O4 anchored on reduced graphene oxide with enhanced performance for peroxymonosulfate activation in ibuprofen degradation

Abstract

Urchin-like Co₃O₄ anchored on reduced graphene oxide was easily prepared with hydrothermal reaction by using a cheap and green agent. First, the surface morphology and physicochemical properties of Co₃O₄-rGO were characterized. Compared with Co₃O₄, Co₃O₄-rGO possessed excellent activity in peroxymonosulfate (PMS) activation for ibuprofen (IBU) degradation. Then, the influences of Co₃O₄-rGO dosage, IBU concentration, PMS concentration and pH on IBU and TOC removal were investigated, respectively. Furthermore, both ·OH and SO₄^•- were identified to be the main active species, and SO₄^•- made the predominant contribution. In addition, residual PMS and SO₄^•- quantification demonstrated that Co₃O₄-rGO could activate PMS more effectively, and produce more SO₄^•-. The mechanistic study revealed that the valence state conversion of Co²⁺/Co³⁺ was the critical PMS activation mechanism. Moreover, the enhanced activity of Co₃O₄-rGO is accounted for the combination of multiple unique characteristics, including excellent electronic transmission (Co²⁺ to Co³⁺, Co²⁺ to PMS), more active sites, and chemical bonds between Co₃O₄ and rGO. 13 degradation products were determined and possible degradation routes were proposed based on the results of LC-MS/MS. Finally, the Co₃O₄-rGO/PMS system also exhibited satisfactory removal of IBU in real water matrices.

Keywords: Degradation; Ibuprofen; Mechanism; PMS; Sulfate radical.