The application of sulfate radical advanced oxidation for organic pollutant removal has been hindered by some shortages such as the recycling difficulty of a powered catalyst, the low utilization efficiency of oxidants, and the secondary pollution (including soil acidification) after reaction. Herein, we fabricate a selective separation catalysis membrane (SSCM) for a highly efficient and environment-friendly persulfate-based advanced oxidation process. The SSCM comprises a top polydimethylsiloxane layer which is selectively penetrable to hydrophobic organic pollutants, followed by a catalyst layer with a magnetic nitrogen-doped porous carbon material, targeting the advanced oxidation of the selected pollutants. Compared with the catalyst in powder form, such SSCM devices significantly reduced the dosage of peroxymonosulfate by more than 40% and the catalyst dosage by 97.8% to achieve 80% removal of phenol with the coexistence of 20 mg L-1 humic acid (HA). The SSCM can extract target pollutants while rejecting HA more than 91.43% for 100 h. The pH value in the receiving solution demonstrated a significant reduction from 7.01 to 3.00. In comparison, the pH value in the feed solution varied from 6.05 to a steady 4.59. The results can be ascribed to the specific functionality for the catalyst anchored, natural organic matter isolation, and reaction compartmentation provided by SSCMs. The developed SSCM technology is beneficial for catalysts reused in remediation practices, saving oxidant dosage, and avoiding acidification of soil and water, thus having tremendous application potential.
Keywords: advanced oxidation; hydrophobic organic pollutant; membrane; peroxymonosulfate; selectivity.