The Shannon entropy in an LS-coupled configuration space has been calculated through a transformation from that in a jj-coupled configuration space for a Ni-like isoelectronic sequence. The sudden change of Shannon entropy, information exchange, eigenlevel anticrossing, and strong configuration interaction have been presented for adjacent levels. It is shown that eigenlevel anticrossing is a sufficient and necessary condition for the sudden change of Shannon entropy, and both of them are a sufficient condition for information exchange, which is the same as the case of the jj-coupled configuration space. It is found that the structure of sudden change from jj-coupled into LS-coupled configuration spaces through the LS-jj transformation is invariant for Shannon entropy along the isoelectronic sequence. What is more, in an LS-coupled configuration space, there are a large number of information exchanges between energy levels whether with or without strong configuration interaction, and most of the ground and single excited states of Ni-like ions are more suitable to be described by a jj-coupled or other configuration basis set instead of an LS-coupled configuration basis set according to the configuration mixing coefficients and their Shannon entropy. In this sense, Shannon entropy can also be used to measure the applicability of a configuration basis set or the purity of atomic state functions in different coupling schemes.
Keywords: LS-coupled configuration space; LS-jj transformation; Shannon entropy; unique notation.