The poor dispersibility and re-dispersibility of cellulose nanofibrils (CNFs) in various solvents and polymers have been recognized as the key factors limiting their potential applications. TEMPO oxidation, as the most common surface modification, can greatly improve the dispersion and re-dispersion of CNFs. However, the diameter of TEMPO-oxidized cellulose nanofibers (TOCNFs) has not been regulated in most researches, which was an important factor determining the dispersion and re-dispersion of TOCNFs. Herein, this work explored the effect of carboxyl groups on dispersion and re-dispersion of TOCNFs with uniform diameter in various solvents. Notably, fractal dimension was innovatively introduced to characterize the distribution of TOCNFs diameter. The fractal dimension and statistic diameter of TCONFs with different carboxyl group contents are ~1.56 and ~22 nm, demonstrating that the diameter of TOCNFs has been regulated in the same range. When the carboxyl group content is up to 1.58 mmol/g, the dispersion and re-dispersion of TOCNFs suspension in water and different organic solvents are the most uniform and stable. In a word, this work explores the dispersion and re-dispersion of TOCNFs with the uniform diameter and different carboxyl group contents, which can provide the theoretical guidance for various potential applications of nanofibrils in polymer matrix composites.
Keywords: Carboxyl group; Diameter; Dispersion; Organic solvents; TEMPO-oxidized cellulose nanofibers.
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