Direct red 89 dye degradation by advanced oxidation process using sulfite and zero valent under ultraviolet irradiation: Toxicity assessment and adaptive neuro-fuzzy inference systems modeling

Abstract

Sulfate-based advanced oxidation process mediated by zero-valent iron (ZVI) and ultraviolet radiation for the decomposition of sulfite salts resulted in the formation of strong oxidizing species (sulfate and hydroxide radicals) in aqueous solution is reported. Degradation of direct red 89 (DR89) dye via UV/ZVI/sulfite process was systematically investigated to evaluate the effect of pH, ZVI dose, sulfite, initial DR89 concentration, and reaction time on DR89 degradation. The synergy factor of UV/ZVI/sulfite process was found to be 2.23-times higher than the individual processes including ZVI, sulfite and UV. By increasing the ZVI dose from 100 mg/L to 300 mg/L, dye degradation was linearly enhanced from 67.12 ± 3.36% to 82.40 ± 4.12% by the UV/ZVI/sulfite process due to enhanced ZVI corrosion and sulfite activation. The highest degradation efficiency of 99.61 ± 0.02% was observed at pH of 5.0, [ZVI]₀ = 300 mg/L, and [sulfite]₀ = 400 mg/L. Toxicity assessment by Lepidium sativum demonstrated that treated dye solution by UV/ZVI/sulfite was within the non-toxic range. The application of optimal adaptive neuro-fuzzy inference system (ANFIS) to predict DR89 degradation indicated high accuracy of ANFIS model (R² = 0.97 and RMSE = 0.051) via the UV/ZVI/sulfite process. It is suggested that UV/ZVI/sulfite process is suitable for industrial wastewater treatment.

Keywords: Adaptive neuro-fuzzy inference system; Direct red 89; Sulfate radicals; Sulfite salts; Toxicity assessment.