Replacing oxygen evolution reaction (OER) by electrooxidations of organic compounds has been considered as a promising approach to enhance the energy conversion efficiency of the electrolytic water splitting proces. Developing efficient electrocatalysts with low potentials and high current densities is crucial for the large-scale productions of H2 and other value-added chemicals. Herein, non-noble metal electrocatalysts Co-doped Ni3 S2 self-supported on a Ni foam (NF) substrate are prepared and used as catalysts for 5-hydroxymethylfurfural (HMF) oxidation reaction (HMFOR) under alkaline aqueous conditions. For HMFOR, the Co0.4 NiS@NF electode achieves an extremely low onset potential of 0.9 V versus reversible hydrogen electrode (RHE) and records a large current density of 497 mA cm-2 at 1.45 V versus RHE for HMFOR. During the HMFOR-assisted H2 production, the yield rates of 2,5-furandicarboxylic acid (FDCA) and H2 in a 10 mL electrolyte containing 10 × 10-3 M HMF are 330.4 µmol cm-2 h-1 and 1000 µmol cm-2 h-1 , respectively. The Co0.4 NiS@NF electrocatalyst displays a good cycling durability toward HMFOR and can be used for the electrooxidation of other biomass-derived chemicals. The findings present a facile route based on heteroatom doping to fabricate high-performance catalyses that can facilitate the industrial-level H2 production by coupling the conventional HER cathodic processes with HMFOR.
Keywords: 5-hydroxymethylfurfural; Co-doping; large current density; phase reconstruction.
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