Sensitivity Analysis in the Microkinetic Description of Electrocatalytic Reactions

J Phys Chem A. 2022 May 5;126(17):2746-2749. doi: 10.1021/acs.jpca.2c00624. Epub 2022 Apr 22.

Abstract

A methodology to determine how the variation in a kinetic parameter affects the global kinetic response of an electrochemical reaction is proposed. The so-called sensitivity analysis is applied to quantify the contribution of single reaction steps of an electrocatalytic system under an oscillatory regime using microkinetic analysis.