Peroxymonosulphate Activation by Basolite ® F-300 for Escherichia coli Disinfection and Antipyrine Degradation

Int J Environ Res Public Health. 2022 Jun 3;19(11):6852. doi: 10.3390/ijerph19116852.


In this study, the removal of persistent emerging and dangerous pollutants (pharmaceuticals and pathogens) in synthetic wastewater was evaluated by the application of heterogeneous Advanced Oxidation Processes. To do that, a Metal-Organic Framework (MOF), Basolite® F-300 was selected as a catalyst and combined with peroxymonosulfate (PMS) as oxidants in order to generate sulphate radicals. Several key parameters such as the PMS and Basolite® F-300 concentration were evaluated and optimized using a Central Composite Experimental Design for response surface methodology for the inactivation of Escherichia coli. The assessment of the degradation of an analgesic and antipyretic pharmaceutical, antipyrine, revealed that is necessary to increase the concentration of PMS and amount of Basolite® F-300, in order to diminish the treatment time. Finally, the PMS-Basolite® F-300 system can be used for at least four cycles without a reduction in its ability to disinfect and degrade persistent emerging and dangerous pollutants such as pharmaceuticals and pathogens.

Keywords: Advanced Oxidation Processes; Basolite® F-300; Escherichia coli; MOF; antipyrine; disinfection; sulphate radicals.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antipyrine
  • Disinfection*
  • Escherichia coli
  • Oxidation-Reduction
  • Peroxides
  • Pharmaceutical Preparations
  • Water Pollutants, Chemical* / analysis


  • Peroxides
  • Pharmaceutical Preparations
  • Water Pollutants, Chemical
  • peroxymonosulfate
  • Antipyrine

Grant support

This research has been financially supported by Project PID2020-113667GBI00, funded by MCIN/AEI/10.13039/501100011033 and Xunta de Galicia, and the European Regional Development Fund (ED431C 2021-43).