Positive Cooperativity Induced by Interstrand Interactions in Silver(I) Complexes with α,α'-Diimine Ligands

Davood Zare; Claude Piguet; Alessandro Prescimone; Catherine E Housecroft; Edwin C Constable

doi:10.1002/chem.202201914

Positive Cooperativity Induced by Interstrand Interactions in Silver(I) Complexes with α,α'-Diimine Ligands

Chemistry. 2022 Jul 26;28(42):e202201914. doi: 10.1002/chem.202201914. Epub 2022 Jun 30.

Authors

Davood Zare¹, Claude Piguet², Alessandro Prescimone¹, Catherine E Housecroft¹, Edwin C Constable¹

Affiliations

¹ Department of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, 4058, Basel, Switzerland.
² Department of Inorganic and Analytical Chemistry, University of Geneva, 30 quai E. Ansermet, 1211, Geneva 4, Switzerland.

PMID: 35773237
DOI: 10.1002/chem.202201914

Abstract

Invited for the cover of this issue are Davood Zare, Claude Piguet, Edwin C. Constable and co-workers at the University of Basel and the University of Geneva. The image depicts a [Ag^I L]⁺ intermediate about to catch a second α,α'-diimine ligand to form the stable [Ag^I L₂ ]⁺ . Read the full text of the article at 10.1002/chem.202200912.

MeSH terms

Humans
Ligands
Silver*

Substances

Ligands
Silver