Multicomponent biodegradable hydrogels based on natural biopolymers as environmentally coating membrane for slow-release fertilizers: Effect of crosslinker type

Abstract

This work aims to explore the suitable crosslinker type for synthesizing multicomponent biodegradable hydrogels of cassava starch (CSt) grafted with acrylic acid (AA) semi-interpenetrated by natural rubber (NR)/polyvinyl alcohol (PVA) blend (CSt-g-PAA/NR/PVA, CSB semi-IPN hydrogel) as coating membranes for slow-release urea fertilizers. Three crosslinker types (ethylene glycol dimethacrylate (EGDMA), glutaraldehyde (GA) and N,N'- methylene-bis-acrylamide (MBA)) were employed to investigate their influences on the properties of CSB semi-IPN hydrogels. The results revealed that the different crosslinkers clearly exhibited different water-retention capacity, biodegradation, slow release and plant growth performance of the CSB semi-IPN hydrogels. The CSB-G2 hydrogel (crosslinked with GA at 2 wt%) remained higher water-retention at 30 days (20.2 %), greater rate of degradation (1.37 %/day) and better biosafety (OD600 = 2.26) compared to CSB-M2 and CSB-E2 hydrogels. After urea pellets were coated by CSB hydrogels and wax layers (UCSBw formulation), the urea release rates from the UCSBw-M2, UCSBw-E2 and UCSBw-G2 formulations in 30 days were 67.7 %, 68.7 % and 78.3 %, respectively, corresponding well with swelling ratio and pore size. Besides, the UCSBw-G2 formulation yielded the greater plant growth performance (height, leaf length and product weight) than other two formulations and commercial fertilizer. In conclusion, GA is the suitable crosslinker for synthesizing the CSB-g-PAA/NR/PVA hydrogels with high water-retention, excellent biodegradation, less negative impact on environments, acceptable slow-release rate, good biosafety and reasonable price for slow-release fertilizers.

Keywords: AA; Biosafety; Kinetics; Natural rubber; PVA; Starch.