Facile synthesis of broom stick like FeOCl/g-C3N5 nanocomposite as novel Z-scheme photocatalysts for rapid degradation of pollutants

Abstract

A simple and cost-effective route has been utilized for the preparation of a novel lamellar structured FeOCl/g-C₃N₅ nanocomposite as Z-scheme photocatalyst. The preparation method was performed under the ambient temperature conditions without any hazardous chemicals. Various characterization techniques, namely XRD, FESEM, TEM, FT-IR, UV-Vis, DRS, and PL were carried out to analyse the nanocomposite for confirmation of FeOCl/g-C₃N₅ nanocomposite. To evaluate its and visible light degradation performances tetracycline (T-C) was used as target pollutant. Among the optimum loading for the g-C₃N₅ incorporated FeOCl binary nanocomposites, the g-C₃N₅/FeOCl exhibited a superlative degradation performance toward the T-C antibiotic pollutant. The results confirmed that 95% of T-C was degraded within 40 min under photodegradation mechanism. The improved photodegradation performance in degradation of T-C was mainly due to the reduction in electron-hole recombination, broadening in the light absorption by g-C₃N₅ incorporation, which leads to shortening the degradation time. Furthermore, the hydroxyl and superoxide radicals played a major role in the photodegradation process and the possible mechanism was elucidated and proposed. The present work implies a novel, sustainable, and efficient Z-scheme system that may deliver a convenient method for environment remediation.

Keywords: G-C(3)N(5); Lamellar FeOCl; Photodegradation; Visible light; Z-Scheme.