Ferroelectrics are considered excellent photocatalytic candidates for solar fuel production because of the unidirectional charge separation and above-gap photovoltage. Nevertheless, the performance of ferroelectric photocatalysts is often moderate. A few studies showed that these types of photocatalysts could achieve overall water splitting. This paper proposes an approach to fabricating interfacial charge-collecting nanostructures on positive and negative domains of ferroelectric, enabling water splitting in ferroelectric photocatalysts. The present study observes efficient accumulations of photogenerated electrons and holes within their thermalization length (~50 nm) around Au nanoparticles located in the positive and negative domains of a BaTiO3 single crystal. Photocatalytic overall water splitting is observed on a ferroelectric BaTiO3 single crystal after assembling oxidation and reduction cocatalysts on the positively and negatively charged Au nanoparticles, respectively. The fabrication of bipolar charge-collecting structures on ferroelectrics to achieve overall water splitting offers a way to utilize the energetic photogenerated charges in solar energy conversion.
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