Is the presence of Cu(II) and p-benzoquinone a challenge for the removal of microplastics from landfill leachate?

Abstract

A large number of plastic wastes generated eventually end up in landfills. The leachate from landfills has become a potential destination for microplastics (MPs). Many researchers have turned their attention to the distribution of MPs in landfill leachate. However, rare researchers mentioned that the efficient removal of MPs in landfill leachate was hard to realized. In this work, we analyzed MPs distribution and composition in leachate from a municipal landfill. Subsequently, to understand the causes of hydrophilization of MPs in leachate, we investigated the flotation percentage of polyvinyl chloride (PVC), polyethylene terephthalate (PET), and polystyrene (PS) MPs when exposure to p-benzoquinone and Cu²⁺. We conducted experiments on factors including the concentration of pollutants, pH, and interaction time. Meanwhile, the adsorption kinetics, adsorption isotherms, and synergistic effects of p-benzoquinone and Cu²⁺ were further investigated. The order of the strength of the hydrophilic effect of contaminants on MPs in leachate was p-benzoquinone + Cu²⁺ > p-benzoquinone > Cu²⁺. The physisorption and chemisorption of p-benzoquinone and Cu²⁺ on the MPs surface, respectively, resulted in the hydrophilization of the MPs surface. The order of hydrophilization and the adsorption capacity for pollutants of the three MPs were consistent: PVC > > PET ≈ PS. We proposed a feasible scheme with the oleic acid to restore the hydrophobicity of MPs, which could increase the removal rate of MPs by 87.37 %. This work revealed the hydrophilization effects of pollutants on MPs and proposed a novel insight into the MPs removal from landfill leachate.

Keywords: Adsorption; Froth flotation; Landfill leachate; Microplastics; Pollutants.