Cellulose-based, flexible polyurethane polyHIPEs with quasi-closed-cell structures and high stability for thermal insulation

Abstract

Cellulose-based, closed-cell porous materials templated from emulsions are promising for thermal insulation, but their low stability imposed by physical interaction hinders the materials from real applications. Herein, we report the fabrication of cellulose-based, flexible polyurethane polyHIPEs with quasi-closed-cell structures, high stability and flexibility for thermal insulation. The polyHIPEs were prepared from cellulose-stabilized Pickering high internal phase emulsions through interfacial crosslinking using isocyanate. The resulting polyurethane polyHIPEs showed controllable external shapes, quasi-closed-cell structures, high flexibility, low density, and robust compression (without fracture even after compression to 30 % original height). The crosslinking enabled the polyHIPEs to show hydrophobicity, good stability (without breakage and dissolution observed after immersing in NaOH solution at pH 12, HCl solution at pH 1 and hot water at 100 °C, for 24 h) and decreased moisture uptake (below 1 %). The low density and quasi-closed-cell structures endowed the polyHIPEs with high thermal insulation, with thermal conductivity as low as 33.1 mW/(m K). These features make the cellulose-based, closed-cell polyHIPEs as an excellent candidate for thermal insulting.

Keywords: Cellulose; Closed-cell structure; Emulsion templating; Interfacial crosslinking; Thermal insulation.