Anodic oxidation of sulfamethoxazole paired to cathodic hydrogen peroxide production

Abstract

A double chamber electrochemical system is developed consisting of a boron-doped diamond (BDD) anode and a graphite cathode, which not only degrades sulfamethoxazole (SMX) but also simultaneously generates hydrogen peroxide (H₂O₂). The degradation of SMX is carried out by (in)direct oxidation at the BDD anode and H₂O₂ is produced by two electron oxygen (O₂) reduction reaction (ORR) at the cathode. The effect of different parameters on the kinetics of both mechanisms was investigated. The performance of the system at the optimized conditions (pH 3, 0.05 M Na₂SO₄ as electrolyte, and 10 mA as applied current) showed that after 180 min of electrolysis, SMX was almost fully degraded (95% removal and ∼90% COD reduction) as well as about 535 μM H₂O₂ was accumulated. With the help of LC-MS, five intermediates formed during SMX electrolysis were properly identified and a degradation pathway was proposed. This study advocates methods for improving the effectiveness of energy use in advanced wastewater treatment.

Keywords: Boron-doped diamond; Electrochemical advanced oxidation processes; Graphite; Hydrogen peroxide; Oxygen reduction reaction; Sulfamethoxazole.