Enhancing the Electrochemical Performance of High Voltage LiNi0.5Mn1.5O4 Cathode Materials by Surface Modification with Li1.3Al0.3Ti1.7(PO4)3/C

Nanomaterials (Basel). 2023 Feb 5;13(4):628. doi: 10.3390/nano13040628.

Abstract

A novel method for surface modification of LiNi0.5Mn1.5O4 (LNMO) was proposed, in which a hybrid layer combined by Li1.3Al0.3Ti1.7(PO4)3 (LATP) and carbon (C) composite on LNMO material were connected by lithium iodide. Structure and morphology analyses illustrated that a higher contact area of active substances was achieved by the LATP/C composite layer without changing the original crystal structure of LNMO. XPS analysis proved that I- promoted the reduction of trace Mn4+, resulting in a higher ion conductivity. Galvanostatic charge-discharge tests exhibited the capacity of the LNMO with 5% LATP/C improved with 35.83% at 25 °C and 95.77% at 50 °C, respectively, compared with the bare after 100 cycles, implying the modification of high-temperature deterioration. EIS results demonstrated that one order of magnitude of improvement of the lithium-ion diffusion coefficient of LATP/C-LNMO was achieved (3.04 × 10-11 S cm-1). In conclusion, the effective low-temperature modification strategy improved the ionic and electronic conductivities of the cathode and suppressed the side reactions of high-temperature treatment.

Keywords: LATP/C composite; LiNi0.5Mn1.5O4 cathode; lithium iodide; low temperature; solvent recrystallization.

Grants and funding

The work was supported by research funding [Project name “211 Project” Special Funding, Project Account Code (#40120411)]; the 111 project (B17034) and Innovative Research Team Development Program of Ministry of Education of China (IRT_17R83).