High-pressure single crystal growth and magnetoelectric properties of CdMn7O12

Abstract

The concurrent presence of large electric polarization and strong magnetoelectric coupling is quite desirable for potential applications of multiferroics. In this paper, we report the growth of CdMn₇O₁₂single crystals by flux method under a high pressure of 8 GPa for the first time. An antiferromagnetic (AFM) order with a polar magnetic point group is found to occur at the onset temperature ofT_N1= 88 K (AFM1 phase). As a consequence, the pyroelectric current emerges atT_N1and gradually increases and reaches its maximum atT_set= 63 K, at which the AFM1 phase finally settles down. BelowT_set, CdMn₇O₁₂single crystal exhibits a large ferroelectric polarization up to 2640µC m^-2. Moreover, the spin-induced electric polarization can be readily tuned by applying magnetic fields, giving rise to considerable magnetoelectric coupling effects. Thus, the current CdMn₇O₁₂single crystal acts as a rare multiferroic system where both large polarization and strong magnetoelectric coupling merge concurrently.

Keywords: high pressure growth; magnetoelectric properties; quadruple perovskite oxides; single crystal.