Cinchona alkaloids - acid, anion-driven fluorescent INHIBIT logic gates with a receptor1-fluorophore-spacer-receptor2 format and PET and ICT mechanisms

RSC Adv. 2023 May 2;13(20):13505-13510. doi: 10.1039/d3ra02704j.

Abstract

The fluorescent natural products, quinine, quinidine, cinchonine and cinchonidine are demonstrated as H+-enabled, halide-disabled (Cl-, Br- or I-) INHIBIT and INHIBIT-OR combinatorial logic gates in water. More fluorescent natural products with intrinsic logic properties await to be discovered.