Photochemical behaviors of dissolved organic matter in aquatic environment: Generation, characterization, influencing factors and practical application

Abstract

Dissolved organic matter (DOM) widely exists in aquatic environment and plays a critical role in environmental photochemical reaction. The photochemical behaviors of DOM in sunlit surface waters have received widely attention because its photochemical effects for some coexisted substances in aquatic environment, especially for organic micropollutants degradation. Therefore, to gain a comprehensive understanding of the photochemical properties and environmental effects of DOM, we reviewed the influence of sources on the structure and composition of DOM with relevant identified techniques to analysis functional groups. Additionally, identification and quantification for reactive intermediates are discussed with a focus on influencing factors to produce reactive intermediates by DOM under solar irradiation. These reactive intermediates can promote the photodegradation of organic micropollutants in the environmental system. In future, attention should be paid to the photochemical properties of DOM and environmental effects in real environmental system and development of advanced techniques to study DOM.

Keywords: Dissolved organic matter; Organic micropollutant; Photochemical transformation; Reactive intermediates.