Synthesis of lithium oxy-thiophosphate solid electrolytes with Li10GeP2S12 structure by a liquid phase process using 2-propanol

Shunichiro Shiba; Akira Miura; Yuta Fujii; Kiyoharu Tadanaga; Kota Terai; Futoshi Utsuno; Hiroyuki Higuchi

doi:10.1039/d3ra03929c

Synthesis of lithium oxy-thiophosphate solid electrolytes with Li₁₀GeP₂S₁₂ structure by a liquid phase process using 2-propanol

RSC Adv. 2023 Jul 28;13(33):22895-22900. doi: 10.1039/d3ra03929c. eCollection 2023 Jul 26.

Authors

Shunichiro Shiba¹, Akira Miura², Yuta Fujii², Kiyoharu Tadanaga², Kota Terai³, Futoshi Utsuno³, Hiroyuki Higuchi³

Affiliations

¹ Graduate School of Chemical Sciences and Engineering, Hokkaido University 060-8628 Hokkaido Japan.
² Faculty of Engineering, Hokkaido University 060-8628 Hokkaido Japan tadanaga@eng.hokudai.ac.jp.
³ Lithium Battery Material Department, Advanced Materials Company, Idemitsu Kosan Company Limited Chiba 299-0293 Japan.

Abstract

Lithium oxy-thiophosphates isostructural with Li₁₀GeP₂S₁₂ (LGPS) were synthesized by a liquid-phase process using 2-propanol as the solvent and Li₂S and P₂S₅ as the starting materials. The XRD and ³¹P NMR results indicate that the synthesized compound has a slightly shrieked LGPS-type crystal structure where sulfur in PS₄^3- is partially replaced by oxygen. The sample synthesized from the nominal composition of Li₂S : P₂S₅ = 2.5 : 1 and at the annealing temperature of 300 °C exhibited the ionic conductivity of 1.6 × 10^-4 S cm^-1 at 25 °C. The synthesized solid electrolyte was found to be electrochemically stable in the potential range of 0-5 V, and also relatively stable under air with low relative humidity.