Microstructure and Superconducting Properties of Bi-2223 Synthesized via Co-Precipitation Method: Effects of Graphene Nanoparticle Addition

Nanomaterials (Basel). 2023 Jul 28;13(15):2197. doi: 10.3390/nano13152197.


The effects of graphene addition on the phase formation and superconducting properties of (Bi1.6Pb0.4)Sr2Ca2Cu3O10 (Bi-2223) ceramics synthesized using the co-precipitation method were systematically investigated. Series samples of Bi-2223 were added with different weight percentages (x = 0.0, 0.3, 0.5 and 1.0 wt.%) of graphene nanoparticles. The samples' phase formations and crystal structures were characterized via X-ray diffraction (XRD), while the superconducting critical temperatures, Tc, were investigated using alternating current susceptibility (ACS). The XRD showed that a high-Tc phase, Bi-2223, and a small low-Tc phase, Bi-2212, dominated the samples. The volume fraction of the Bi-2223 phase increased for the sample with x = 0.3 wt.% and 0.5 wt.% of graphene and slightly reduced at x = 1.0 wt.%. The ACS showed that the onset critical temperature, Tc-onset, phase lock-in temperature, Tcj, and coupling peak temperature, TP, decreased when graphene was added to the samples. The susceptibility-temperature (χ'-T) and (χ″-T) curves of each sample, where χ' and χ″ are the real and imaginary parts of the susceptibility, respectively, were obtained. The critical temperature of the pure sample was also measured.

Keywords: Bi-2223; co-precipitation method; critical current; critical temperature; graphene nanoparticles.