Due to miscellaneous toxic gases in the vicinity, there is a burgeoning need for advancement in the existing gas sensing technology not only for the survival of mankind but also for the industries based in various fields such as beverage, forestry, health care, environmental monitoring, agriculture, and military security. A gas sensor must be highly selective toward a specific gas in order to avoid incorrect signals while responding to nontarget gases. This may lead to complex scenarios depicting sensor defects, such as low selectivity and cross-sensitivity. Therefore, a multiplex gas sensor is required to address the problems of cross selectivity by combining different gas sensors, signal processing, and pattern recognition techniques along with the currently employed gas sensing technologies. The different sensing materials used in these sensor arrays will produce a unique response signal for developing a set of identifiers as the input that can be used to recognize a specific gas by its "fingerprint". This review provides a comprehensive review of chemiresistive-based multiplex gas sensors, including various fabrication strategies from expensive to low-cost techniques, advances in sensing materials, and a gist of various pattern recognition techniques used for both rigid and flexible gas sensor applications. Finally, the review assesses the current state-of-the-art in multiplex gas sensor technology and discusses various challenges for future research in this direction.
Keywords: chemiresistive sensors; cross selectivity; gas sensor; interdigitated electrodes; microsystem; multisensor array; pattern recognition; toxic gas.