Salinity origin in the coastal aquifer of the Southern Venice lowland

Sci Total Environ. 2023 Dec 20:905:167058. doi: 10.1016/j.scitotenv.2023.167058. Epub 2023 Sep 13.

Abstract

Groundwater salinization can be natural and anthropogenic in origin, although it often results from a combination of both, especially in low-lying coastal regions that are hydraulically controlled. This study proposes a method to assess the origin of salinity using environmental tracers in porewater, like Cl- and Br-, combined with depositional facies associations detected in sediment cores. Such integrated approach was tested in a target area south of the Venice Lagoon (Italy), where groundwater salinization is triggered by multiple mechanisms due to the complexity of the hydro-geomorphological environment. Batch tests were performed on sediment core samples from boreholes to quantify major anions and total inorganic N. Cl- and Br- porewater concentrations coupled with sedimentary facies association provided insights into the origin of groundwater salinity from a variety of sources, including past and present seawater intrusion, agricultural leaching, and evaporites. The strengths and limitations of the integrated approach are discussed to provide a pathway for improving water resource management and planning measures to prevent groundwater salinization in coastal areas.

Keywords: Aquifer salinization; Cl(−)/Br(−) molar ratio; Depositional environments; Sediment porewater.