Ultra-sensitive detection and scavenging of arsenic ions and ciprofloxacin using 3D multipurpose hemicellulose based aerogel: Adsorption mechanism and RSM optimization

Abstract

Trace level detection and efficient removal of arsenite ions (As (III)) and ciprofloxacin (CPR) antibiotic was achieved using hemicellulose based ratiometric fluorescent aerogel. Hemicellulose derived from rice straw was oxidised to dialdehyde hemicellulose followed by crosslinking using chitosan via a Schiff base reaction (C = N) yielding a highly porous 3D fluorescent aerogel (CS@DAHCA). Various factors governing adsorption were analyzed by applying response surface methodology (RSM) approach. CS@DAHCA exhibited ultra-trace level monitoring with the limit of detection of 3.529 pM and 55.2 nM for As (III) and CPR, respectively. The CS@DAHCA showed maximum adsorption capacity of 185 μg g^-1 and 454 mg g^-1 for As (III) and CPR, respectively. Finally, the feasibility of CS@DAHCA was ascertained for real water samples confirming it as promising candidate for remediation of As (III) and CPR.

Keywords: As (III) metal ion, ciprofloxacin; Biomass derived hemicellulose; Multipurpose hydrogel; Sensing and adsorption.