Synthesis of spiro[indolenine]-methanofullerenes via Deoxofluor promoted deoxygenative cyclopropanation of 1,2-(3-indole)-fullerenols

Wen-Bin Ma; Long-Ge Wang; Shou-Rui Chen; Xiang Zhang; Jun Xuan; Fei Li

doi:10.1039/d3ob01697h

Synthesis of spiro[indolenine]-methanofullerenes via Deoxofluor promoted deoxygenative cyclopropanation of 1,2-(3-indole)-fullerenols

Org Biomol Chem. 2023 Dec 6;21(47):9459-9462. doi: 10.1039/d3ob01697h.

Authors

Wen-Bin Ma¹, Long-Ge Wang¹, Shou-Rui Chen¹, Xiang Zhang¹, Jun Xuan¹, Fei Li¹

Affiliation

¹ Department of Chemistry, Anhui University; Key Laboratory of Structure and Functional Regulation of Hybrid Materials (Anhui University), Ministry of Education; Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Key Laboratory of Functional Inorganic Materials of Anhui Province, Hefei, Anhui 230601, China. lfe@ahu.edu.cn.

PMID: 37997156
DOI: 10.1039/d3ob01697h

Abstract

Deoxofluor-promoted intramolecular cyclopropanation of 1,2-(3-indole)fullerenols has been developed as a straightforward and efficient protocol for the synthesis of various spiro[indolenine]-methanofullerenes. This approach exhibits low cost, operational simplicity, and convenient conditions, and thus has potential application value.