Comparison of tensile properties and porcelain bond strength in metal frameworks fabricated by selective laser melting using three different Co-Cr alloy powders

Abstract

Statement of problem: The selective laser melting (SLM) manufacturing technique has been widely employed to produce Co-Cr dental metal frameworks. The selection of Co-Cr alloy powders has the potential to influence the microstructure and tensile properties, consequently impacting the bond strength of the metal-porcelain. However, limited information is available regarding the effect of Co-Cr alloy powder on these properties when all other factors remain consistent.

Purpose: The purpose of this in vitro study was to assess how the choice of Co-Cr alloys during SLM manufacturing influences the microstructure, tensile properties, and bond strength of metal-ceramic combinations.

Material and methods: Three different Co-Cr alloy powders, Co-Cr-Mo, Co-Cr-Mo-W, and Co-Cr-W were selected in this study. The powder characteristics and chemical compositions were analyzed using a scanning electron microscope (SEM) and energy dispersive X-ray (EDX) analysis, respectively. Subsequently, 12×12×15-mm cube specimens, cylindrical tensile test specimens, and 25×3×0.5-mm metal strips were fabricated using the SLM technique. Microstructural investigations of the cube specimens were conducted after metallographic preparation using SEM. The cylindrical tensile specimens (n=8) from each composition were subjected to tensile tests at a deformation rate of 0.5 mm/min. Following the application of ceramic to the metal specimens (n=10) in each group, the strength of the metal-ceramic bond was evaluated through a 3-point bend test conducted at a crosshead speed of 1 mm/min. Mechanical properties obtained from the tensile tests and bond strength values were statistically analyzed using a one-way ANOVA and Tukey post hoc comparison tests (α=.05).

Results: Melt pool boundaries, columnar and equiaxed grains, and precipitates were observed in the microstructures of 3 different alloys produced by SLM. The Co-Cr-Mo-W alloy had more uniformly dispersed and finely distributed precipitates compared with other alloy compositions. The Co-Cr-Mo-W alloy had exhibited the highest yield strength (1068.0 ±41.2 MPa) and ultimate tensile strength (1263.4 ±10.7 MPa) while showing the lowest ductility under the tensile tests (6.1 ±0.9%) among all 3 alloys. Significant differences in the tensile mechanical properties were observed in the alloys except between the yield strength of the Co-Cr-Mo and Co-Cr-W alloys. The highest elongation (8.9 ±1.2%) was seen in the Co-Cr-Mo alloy. However, no significant differences were detected regarding the bond strength of all 3 groups (P>.05). The mean bond strength values were approximately 42 MPa for all the alloys.

Conclusions: The results indicate that the selection of different Co-Cr alloy powders used in SLM production may influence both microstructure and tensile properties. However, the strength of the metal-ceramic bond of Co-Cr alloys remained unaffected by this selection.