Evaluation of some heavy metals and selenium pollution in Karataş Lake (Burdur/Türkiye) using various pollution indices and statistical analysis

Abstract

Wetland face environmental problems due to some reasons such as drought, rapid population and rapid developments in technology. Karataş Lake is located within the Lakes Region in Türkiye and has also of great economically, ecologically and ornithologically importance. Unfortunately, it completely dried out in 2021 due to sufficient rainfall, groundwater withdrawal and global climate change. In 2022, the lake started to hold water again. This study is important because it is one of the last studies before the lake dries up and first study to evaluate some heavy metals and selenium pollution using some indices. In this study, which was carried out between October 2019-July 2020, some heavy metals and selenium concentrations were determined in water of Karataş Lake seasonally and evaluated pollution degree of lake water using some indices and statistical analysis. Water temperature, pH, electrical conductivity and dissolved oxygen levels were measured in situ using YSI 556 MPS. For heavy metal analysis, water samples were taken, acidified to a pH of <2, stored at 4 °C and analyzed directly using ICP-OES (Agilent 5110). Pb and Se in all seasons were below detection limit. The analyzed metals sorted as; Cd < Mo < Cr < Cu < Mn < Zn < Ni < Fe. Generally, heavy metals were increased in autumn and decreased in spring. According to some water quality standards for drinking water, Fe levels were higher than the permissible levels for drinking water in all seasons (TSE, 2005; EPA, 2018; EU, 2020), Mn in autumn (TSE, 2005; EPA, 2018; EU, 2020), Ni in autumn and summer (TSE, 2005; EU, 2020). Water Quality Index (WQI), Heavy Metal Pollution Index (HPI) and Heavy Metal Evaluation Index (HEI) values were calculated in Karataş Lake to determine pollution degree. Depend on WQI results, lake water was in good category in autumn, winter and spring while poor category in summer. The lake water samples based on HPI and HEI values are in the low contamination category. The lake is still struggling with environmental problems. If necessary precautions are not taken for the future of the lake, the lake may dry out again. The results of this study will help the authorities in terms of preventing re-drying, sustainability of the lake and management of the region. This study will be also a reference for future studies.

Keywords: Heavy metal; Karataş Lake; Pollution index; Risk assessment; Türkiye.