Investigating the potential of mineral precipitation in co-pyrolysis biochar: Development of a novel Cd (II) adsorption material utilizing dual solid waste

Bioresour Technol. 2024 Jun:402:130762. doi: 10.1016/j.biortech.2024.130762. Epub 2024 Apr 29.

Abstract

Ionic cadmium (Cd (II)) in water is a significant threat to ecosystems, the environment, and human health. Research is currently focused on developing efficient adsorption materials to combat Cd (II) pollution in water. One promising solution involves co-pyrolyzing solid residue from anaerobic digestion of food waste with oil-based drill cuttings pyrolysis residue to create a biochar with high organic matter content. This biochar has a lower heavy metal content and leaching toxicity compared to China's national standards, making it both safe and resourceful. It exhibits a high adsorption capacity for Cd (II) in water, reaching up to 47.80 ± 0.37 mg/g. Raising the pyrolysis temperature above 600 °C and increasing the amount of pyrolysis residue beyond 30 % enhances the biochar's adsorption capacity. The adsorption process is primarily driven by mineral precipitation, offering a promising approach for dual waste resource management and reducing heavy metal pollution.

Keywords: Co-pyrolysis biochar; Food waste; Heavy metal adsorption; Ionic cadmium; Oil-based drill cuttings.

MeSH terms

  • Adsorption
  • Cadmium* / chemistry
  • Charcoal* / chemistry
  • Chemical Precipitation
  • Minerals / chemistry
  • Pyrolysis
  • Solid Waste*
  • Water Pollutants, Chemical / chemistry
  • Water Purification / methods

Substances

  • Cadmium
  • Charcoal
  • biochar
  • Solid Waste
  • Water Pollutants, Chemical
  • Minerals