Noble Gas Anions: An Overview of Strategies and Bonding Motifs

Chem Asian J. 2024 Jul 15;19(14):e202400191. doi: 10.1002/asia.202400191. Epub 2024 Jun 11.

Abstract

This review article aims to provide an overview of the strategies employed to prepare noble gas anions under different environments and experimental conditions, and of the bonding motifs typically occurring in these species. Observed systems include anions fixed into synthesized salts, detected in the gas phase or in high-pressure devices. The major role of the theoretical calculations is also highlighted, not only in support of the experiments, but also as effective in predicting still unreported species. The chemistry of noble gas anions overall appears as a varied and rich paint, offering fascinating opportunities for both experimentalists and theoreticians.

Keywords: gas-phase chemistry; high-pressure chemistry; noble gas anions; synthetic chemistry; theoretical calculations.

Publication types

  • Review