A Superparamagnetic Composite Hydrogel Scaffold as In Vivo Dynamic Monitorable Theranostic Platform for Osteoarthritis Regeneration

Adv Mater. 2024 Aug;36(35):e2405641. doi: 10.1002/adma.202405641. Epub 2024 Jul 6.

Abstract

Osteoarthritis (OA) is a prevalent disease, characterized by subchondral fractures in its initial stages, which has no precise and specific treatment now. Here, a novel multifunctional scaffold is synthesized by photopolymerizing glycidyl methacrylate-modified hyaluronic acid (GMHA) as the matrix in the presence of hollow porous magnetic microspheres based on hydroxyapatite. In vivo subchondral bone repairing results demonstrate that the scaffold's meticulous design has most suitable properties for subchondral bone repair. The porous structure of inorganic particles within the scaffold facilitates efficient transport of loaded exogenous vascular endothelial growth factor (VEGF). The Fe3O4 nanoparticles assembled in microspheres promote the osteogenic differentiation of bone marrow mesenchymal stem cells and accelerate the new bone generation. These features enable the scaffold to exhibit favorable subchondral bone repair properties and attain high cartilage repair scores. The therapy results prove that the subchondral bone support considerably influences the upper cartilage repair process. Furthermore, magnetic resonance imaging monitoring demonstrates that Fe3O4 nanoparticles, which are gradually replaced by new bone during osteochondral defect repair, allow a noninvasive and radiation-free assessment to track the newborn bone during the OA repair process. The composite hydrogel scaffold (CHS) provides a versatile platform for biomedical applications in OA treatment.

Keywords: composite scaffolds; hydrogel; osteoarthritis; superparamagnetic particles; tissue engineering.

MeSH terms

  • Animals
  • Bone Regeneration / drug effects
  • Cell Differentiation / drug effects
  • Durapatite / chemistry
  • Epoxy Compounds
  • Hyaluronic Acid* / chemistry
  • Hydrogels* / chemistry
  • Magnetic Resonance Imaging
  • Magnetite Nanoparticles / chemistry
  • Magnetite Nanoparticles / therapeutic use
  • Mesenchymal Stem Cells* / cytology
  • Methacrylates / chemistry
  • Microspheres
  • Osteoarthritis* / therapy
  • Osteogenesis / drug effects
  • Porosity
  • Rabbits
  • Theranostic Nanomedicine*
  • Tissue Scaffolds* / chemistry
  • Vascular Endothelial Growth Factor A / metabolism

Substances

  • Hydrogels
  • Hyaluronic Acid
  • Magnetite Nanoparticles
  • Vascular Endothelial Growth Factor A
  • Methacrylates
  • Durapatite
  • glycidyl methacrylate
  • Epoxy Compounds