Concentration-dependent luminescence characterization of terbium-doped strontium aluminate nanophosphors

Luminescence. 2024 Jul;39(7):e4820. doi: 10.1002/bio.4820.

Abstract

The present investigation describes the synthesis of luminescent terbium-doped strontium aluminate nanoparticles emitting bright green light, which were synthesized through a solid-state reaction method assisted by microwave radiation. Various samples containing different concentrations of Tb were synthesized, and an analysis of their structural and morphological features was conducted using powder x-ray diffraction, Fourier transform infrared spectroscopy and field emission scanning electron microscopy. The band gaps of the samples were determined utilizing the Kubelka-Munk method. The quenching mechanism observed was identified to be due to dipole-dipole interaction using the Dexter theory. The optimized sample with a terbium concentration of 4 at.% has a luminescence lifetime of 1.05 ms with 20.62% quantum efficiency. The results of this study indicate that the terbium-doped strontium aluminate fluorescent nanoparticles exhibit promising potential for a wide range of applications, including bioimaging, sensing and solid-state lighting.

Keywords: CIE coordinates; fluorescence; microwave‐assisted solid‐state reaction; nanophosphors; strontium aluminate; terbium.

MeSH terms

  • Aluminum Compounds / chemistry
  • Luminescence*
  • Luminescent Agents / chemical synthesis
  • Luminescent Agents / chemistry
  • Luminescent Measurements
  • Nanoparticles* / chemistry
  • Particle Size
  • Spectroscopy, Fourier Transform Infrared
  • Strontium* / chemistry
  • Terbium* / chemistry

Substances

  • Terbium
  • Strontium
  • Luminescent Agents
  • Aluminum Compounds