Sludge reduction, nitrous oxide emissions, and phosphorus removal by oxic-settling-anaerobic (OSA) process: the effect of hydraulic retention time

Environ Sci Pollut Res Int. 2024 Jul;31(35):48484-48496. doi: 10.1007/s11356-024-34393-5. Epub 2024 Jul 20.

Abstract

This paper presents a study on reducing sewage sludge by an oxic-settling-anaerobic (OSA) pilot plant compared to the conventional activated sludge (CAS) process in view of resource recovery and moving towards plant carbon neutrality. The OSA plant was supplied with real wastewater and the anaerobic reactor was operated under two hydraulic retention times (HRT) (4 and 6 h). Greenhouse gas (GHG) emissions were monitored for the first time to determine the OSA process's production mechanism. The results highlighted that under the lowest HRT (4 h), the removal efficiencies of COD and PO4-P, increased from 75 to 89% and from 39 to 50% for CAS and OSA configurations, respectively. The observed yield coefficient was reduced from 0.58 gTSS gCOD-1 (CAS period) to 0.31 gTSS gCOD-1 (OSA period). A remarkable deterioration of nitrification efficiency under OSA configuration was obtained from 79% (CAS) to 27% (OSA with HRT of 6 h). The huge deterioration of nitrification significantly affected the GHG emissions, with the N2O-N fraction increasing from 1% (CAS) to 1.55% (OSA 4 h HRT) and 3.54% (OSA 6 h HRT) of the overall effluent nitrogen, thus suggesting a relevant environmental implication due to the high global warming potential (GWP) of N2O.

Keywords: Greenhouse gas emission; Nutrient removal; Oxic-settling-anaerobic process; Sludge reduction; Wastewater treatment.

MeSH terms

  • Anaerobiosis
  • Bioreactors
  • Nitrous Oxide*
  • Phosphorus*
  • Sewage* / chemistry
  • Waste Disposal, Fluid* / methods
  • Wastewater / chemistry

Substances

  • Nitrous Oxide
  • Sewage
  • Phosphorus
  • Wastewater