The clinical-grade CBP/ p300 inhibitor CCS1477 represses the global NRF2-dependent cytoprotective transcription program and re-sensitizes cancer cells to chemotherapeutic drugs

Free Radic Biol Med. 2025 Jun:233:102-117. doi: 10.1016/j.freeradbiomed.2025.03.034. Epub 2025 Mar 22.

Abstract

Constitutive activation of NRF2 provides a selective advantage to malignant tumour clones through the hijacking of the NRF2-dependent cytoprotective transcriptional program, which allows the cancer cells to survive and thrive in the chemically stressful tumour niche, whilst also providing resistance to anti-cancer drugs due to the upregulation of xenobiotic metabolizing enzymes and drug efflux pumps. Through a small-molecule epigenetic screen carried out in KEAP1 mutant lung cancer cells, in this study, we identified CCS1477 (Inobrodib) to be an inhibitor of the global NRF2-dependent transcription program. Mechanistically, CCS1477 is able to repress NRF2's cytoprotective response through the inhibition of its obligate transcriptional activator partner CBP/p300. Importantly, in addition to repressing NRF2-dependent anti-oxidative stress and xenobiotic metabolizing enzyme gene expression, CCS1477 treatment is also able to reverse the chemoresistance phenotype and re-sensitize NRF2-activated tumour cells to anti-cancer drugs. Furthermore, in co-culture experiments of KEAP1 mutant cancer cells with primary human T cells, CCS1477 treatment suppressed the acquisition of the T cell exhaustion transcriptional state, which should function to augment the anti-cancer immune response. Thus, CCS1477-mediated inhibition of CBP/p300 represents a novel therapeutic strategy with which to target the currently untreatable tumours with aberrant NRF2 activation.

Keywords: CBP; CCS1477; Drug resistance; Inobrodib; KEAP1; NFE2L2; NRF2; T cell exhaustion; p300.

MeSH terms

  • Antineoplastic Agents* / pharmacology
  • Cell Line, Tumor
  • Drug Resistance, Neoplasm / drug effects
  • Drug Resistance, Neoplasm / genetics
  • E1A-Associated p300 Protein* / antagonists & inhibitors
  • Gene Expression Regulation, Neoplastic / drug effects
  • Humans
  • Imidazoles
  • Kelch-Like ECH-Associated Protein 1 / genetics
  • Lung Neoplasms* / drug therapy
  • Lung Neoplasms* / genetics
  • Lung Neoplasms* / metabolism
  • Lung Neoplasms* / pathology
  • NF-E2-Related Factor 2* / genetics
  • NF-E2-Related Factor 2* / metabolism
  • Oxazoles
  • Oxidative Stress / drug effects
  • Transcription, Genetic / drug effects
  • p300-CBP Transcription Factors* / antagonists & inhibitors
  • p300-CBP Transcription Factors* / genetics

Substances

  • NF-E2-Related Factor 2
  • NFE2L2 protein, human
  • Kelch-Like ECH-Associated Protein 1
  • KEAP1 protein, human
  • Antineoplastic Agents
  • p300-CBP Transcription Factors
  • E1A-Associated p300 Protein
  • CCS1477
  • Imidazoles
  • Oxazoles