The oxidation degradation by unsaturated metal atoms or dangling bonds at MXene edges and defects severely hinders the practical application of MXene. Herein, a passivation scheme for Ti3C2T x MXene is demonstrated by utilizing a sulfhydryl-containing molecule, β-mercaptoethanol (BME), which can significantly suppress the Ti3C2T x oxidation in various environments, including long-term storage of Ti3C2T x aqueous dispersions (2 m), single-layer Ti3C2T x -based devices in humid air (2 m), and high-temperature environment (12 h). Notably, the nonionic BME does not cause aggregation but maintains the 2D morphology of Ti3C2T x . A comprehensive investigation of the protection mechanism through density functional theory (DFT) calculations and experimental characterizations reveals that BME is adsorbed especially at the edges and surface defects of MXene (binding energy -1.70 and -1.05 eV), where the degradation starts. Further, the electron-donating effect of sulfhydryl groups tunes the work function of Ti3C2T x from 4.70 to 4.39 eV, resulting in improved carrier-transport performances in MoS2 field-effect transistors owing to band alignment, where BME-Ti3C2T x serves as the source electrode. The described methodology can largely contribute to the ultralong service life of 2D Ti3C2T x without affecting its excellent properties, thereby promoting the practical application of this emerging material.
Keywords: MXene; Ti—S bond; stability; work function; β-mercaptoethanol.
© 2022 The Authors. Small Science published by Wiley‐VCH GmbH.