ROS-responsive MnO2 mesoporous hydrogel to modulate liver-muscle crosstalk and mitigate NAFLD-associated sarcopenia via exosomal miR-582-5p delivery

Theranostics. 2025 Mar 21;15(10):4579-4592. doi: 10.7150/thno.108280. eCollection 2025.

Abstract

Background: The interrelation between non-alcoholic fatty liver disease (NAFLD) and sarcopenia has emerged as a significant concern due to its systemic impact on metabolic health. However, therapeutic approaches targeting the liver-muscle axis remain underdeveloped. Oxidative stress and inflammatory pathways are key mediators of this crosstalk, exacerbating disease progression. This study aims to develop a reactive oxygen species (ROS)-responsive MnO2 mesoporous PD (HA) hydrogel to modulate this axis and investigate its therapeutic efficacy in NAFLD-associated sarcopenia. Methods: MnO2 mesoporous PD (HA) hydrogels were synthesized with ROS-sensitive properties and characterized for rheological, fluorescence, and conductivity responses. A HepG2-C2C12 co-culture model mimicked the NAFLD-muscle wasting interplay, while high-fat diet (HFD)-induced NAFLD mouse models were used for in vivo evaluations. Cellular stress markers, exosomal miR-582-5p signaling, and atrogenic pathways were assessed using immunofluorescence, qRT-PCR, and histological analyses. Results: Pathway analysis of HFD-induced NAFLD showed upregulation of lipid metabolism and inflammatory signaling, promoting muscle atrophy via exosomal miR-582-5p. The MnO2 mesoporous hydrogel significantly reduced oxidative stress and inflammation in the HepG2-C2C12 co-culture. In vivo, hydrogel implantation in HFD mice mitigated hepatic fibrosis, reduced ROS accumulation, preserved muscle fiber integrity, and downregulated atrogenic markers. Conclusions: The MnO2 mesoporous PD (HA) hydrogel presents a dual-targeting therapeutic strategy for NAFLD and sarcopenia by attenuating oxidative stress and modulating liver-muscle axis signaling. These findings provide a foundation for innovative interventions targeting metabolic comorbidities.

Keywords: Exosomal Delivery; Hydrogel; NAFLD; ROS; Sarcopenia; miR-582-5p.

MeSH terms

  • Animals
  • Diet, High-Fat / adverse effects
  • Disease Models, Animal
  • Exosomes / metabolism
  • Hep G2 Cells
  • Humans
  • Hydrogels* / chemistry
  • Hydrogels* / pharmacology
  • Liver* / drug effects
  • Liver* / metabolism
  • Liver* / pathology
  • Male
  • Manganese Compounds* / chemistry
  • Manganese Compounds* / pharmacology
  • Mice
  • Mice, Inbred C57BL
  • MicroRNAs* / genetics
  • MicroRNAs* / metabolism
  • Non-alcoholic Fatty Liver Disease* / complications
  • Non-alcoholic Fatty Liver Disease* / drug therapy
  • Non-alcoholic Fatty Liver Disease* / metabolism
  • Oxidative Stress / drug effects
  • Oxides* / chemistry
  • Oxides* / pharmacology
  • Reactive Oxygen Species* / metabolism
  • Sarcopenia* / drug therapy
  • Sarcopenia* / etiology
  • Sarcopenia* / metabolism

Substances

  • MicroRNAs
  • Reactive Oxygen Species
  • Hydrogels
  • manganese dioxide
  • Manganese Compounds
  • Oxides