BAY11-7082 Targets RNF25 to Reverse TRIP4 Ubiquitination-dependent NF-κB Activation and Apoptosis Resistance in Renal Cell Carcinoma

Int J Biol Sci. 2025 Jul 4;21(10):4410-4427. doi: 10.7150/ijbs.115032. eCollection 2025.

Abstract

NF-κB pathway dysregulation, a common driver of therapy resistance in cancer, promotes survival by suppressing apoptosis. While the anti-apoptotic role of NF-κB is recognized, the molecular mechanisms underlying this process remain poorly defined. Here, we identify the E3 ubiquitin ligase RNF25 as a key mediator of NF-κB-dependent apoptosis resistance in renal cell carcinoma cells, enabling evasion of multiple targeted therapies. Mechanistically, RNF25 binds TRIP4 and catalyzes its non-degradative ubiquitination at lysine 135, disrupting TRIP4-p65 interactions. This modification liberates p65 to activate NF-κB signaling, upregulating anti-apoptotic effectors (e.g., cIAP2, Bcl-2). We further demonstrate that the NF-κB inhibitor BAY11-7082 directly interacts with RNF25, reversing its pro-survival effects and restoring apoptosis sensitivity. Our findings establish RNF25 as a druggable orchestrator of therapy resistance through NF-κB pathway modulation and propose pharmacological targeting of RNF25 by BAY11-7082 as a strategy to overcome apoptosis resistance in renal malignancies.

Keywords: BAY11-7082; NF-κB activation; RNF25; TRIP4; anti-apoptosis.

MeSH terms

  • Apoptosis / drug effects
  • Carcinoma, Renal Cell* / drug therapy
  • Carcinoma, Renal Cell* / metabolism
  • Cell Line, Tumor
  • Humans
  • Kidney Neoplasms* / drug therapy
  • Kidney Neoplasms* / metabolism
  • NF-kappa B* / metabolism
  • Nitriles* / pharmacology
  • Signal Transduction / drug effects
  • Sulfones* / pharmacology
  • Transcription Factors* / metabolism
  • Ubiquitin-Protein Ligases* / genetics
  • Ubiquitin-Protein Ligases* / metabolism
  • Ubiquitination / drug effects

Substances

  • Sulfones
  • 3-(4-methylphenylsulfonyl)-2-propenenitrile
  • NF-kappa B
  • Ubiquitin-Protein Ligases
  • Nitriles
  • Transcription Factors