The role of aging biomarkers and reproductive hormones in the association between microcystin-LR exposure and semen quality

J Hazard Mater. 2025 Nov 5:499:140075. doi: 10.1016/j.jhazmat.2025.140075. Epub 2025 Oct 8.

Abstract

Toxicological evidence suggests that microcystin-LR (MC-LR) may impair male reproductive function, but epidemiological data remain limited. We conducted a cross-sectional study in Henan Province to investigate the effects of MC-LR exposure on semen quality and the potential mediating roles of aging biomarkers, including sperm mitochondrial DNA copy number (mtDNAcn) and telomere length (TL), as well as reproductive hormones. Urinary MC-LR concentrations were measured using a newly developed ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method. Generalized linear models were used to evaluate associations, and mediation analysis was conducted to quantify indirect effects. Furthermore, the role of oxidative stress in MC-LR-induced alterations of mtDNAcn and TL was examined in vitro using GC-1 cells. MC-LR exposure was associated with adverse changes in semen quality, reproductive hormones, and aging biomarkers. Mediation analysis revealed that follicle-stimulating hormone, sperm mtDNAcn, and sperm TL mediated the effects of MC-LR on the decline in semen quality (mediation proportion 8 %-55 %). Moreover, certain doses of MC-LR increased ROS, mtDNAcn, and TL in GC-1 cells, which were partially reversed by the antioxidant N-Acetyl-L-cysteine. These findings provide new evidence linking environmental MC-LR exposure to impaired male reproductive health, possibly attributable to accelerated aging processes mediated by oxidative stress.

Keywords: Follicle stimulating hormone; Microcystin-LR; Mitochondrial DNA copy number; Semen quality; Telomere length.

MeSH terms

  • Adult
  • Aging*
  • Biomarkers / metabolism
  • Biomarkers / urine
  • Cross-Sectional Studies
  • DNA, Mitochondrial / genetics
  • Follicle Stimulating Hormone / blood
  • Humans
  • Male
  • Marine Toxins
  • Microcystins* / toxicity
  • Microcystins* / urine
  • Oxidative Stress / drug effects
  • Reactive Oxygen Species / metabolism
  • Semen / drug effects
  • Semen Analysis
  • Spermatozoa / drug effects
  • Spermatozoa / metabolism

Substances

  • Microcystins
  • cyanoginosin LR
  • Biomarkers
  • Marine Toxins
  • DNA, Mitochondrial
  • Reactive Oxygen Species
  • Follicle Stimulating Hormone