Polyethylene-grafted poly(hexamethylene guanidine) modified ultra-high molecular weight polyethylene monofilaments and their antimicrobial properties

R Soc Open Sci. 2025 Oct 29;12(10):250340. doi: 10.1098/rsos.250340. eCollection 2025 Oct.

Abstract

Biofouling on netting poses a significant challenge, as it can considerably increase the weight of the nets and shorten their service lifespan. This study investigates the properties of polyethylene-grafted poly(hexamethylene guanidine) (PE-g-PHMG) modified ultra-high molecular weight polyethylene (UHMWPE) monofilaments. The results show that the addition of PE-g-PHMG decreases the degree of crystallinity, average lattice spacing and crystallite size of the blend monofilaments, leading to relatively low rigidity and high toughness. The incorporation of PE-g-PHMG enhances both the knot strength (increased by 17.9%) and the overall antibacterial performance (efficacy rates of 99.4% and 97.2% against Escherichia coli and Staphylococcus aureus) of the blend monofilaments. Furthermore, blend monofilaments (UHMWPE-20%) after washing 30 times exhibit high efficacy rates against E. coli and S. aureus. This article provides a method for preparing fishing grade polyethylene monofilaments that effectively combines favourable characteristics, including enhanced knot strength and good antibacterial properties.

Keywords: antibacterial properties; knot strength; polyethylene-grafted poly(hexamethylene guanidine); ultra-high molecular weight polyethylene monofilaments.

Associated data

  • figshare/10.6084/m9.figshare.c.7963802