The sluggish kinetics and poor stability of the oxygen reduction reaction (ORR) remain the primary bottleneck for achieving high performance in protonic ceramic fuel cells (PCFCs) at intermediate temperatures (400-650°C). In this work, a Pr-based nanocomposite cathode comprised of simple perovskite phase (PrNi0.7Co0.3O3-δ) and Ruddlesden-Popper phase (Co-doped Pr4Ni3O10+δ) is developed. Although PrNi0.7Co0.3O3-δ solely stands as a good cathode with facile proton transfer, combining the superior catalytic activity against oxygen on the Ruddlesden-Popper phase boosts the ORR performance further. The designed nanocomposite cathode outperforms the simple perovskite cathode, attributed to enhanced oxygen absorption and surface diffusion with the Ruddlesden-Popper phase. A precursor-based cathode deposition technique is also developed to achieve cathode grain sizes of ∼100 nm. A single cell with the nanocomposite cathode delivers a peak power density of 1.38 W cm-2 at 650°C, among the highest in reported PCFCs with Pr-based cathodes, with a small degradation rate of 0.145 mV h-1 during 250 h stability test. Further investigation of cathode-electrolyte interface revealed interfacial PrO2 phase formation, promoted by abundant Pr6O11 in the nanocomposite precursor powder, thereby improving both ohmic resistance and stability. These findings highlight the effectiveness of the nanocomposite cathode and underscore its advantages on interfacial properties.
Keywords: Ruddlesden‐Popper phase; catalytic electrode; cathodes; nanocomposites; one‐pot sol–gel synthesis; perovskite; protonic ceramic fuel cell.
© 2026 The Author(s). Small published by Wiley‐VCH GmbH.