Recently discovered cathode materials with antiperovskite (AP) structure have shown a promising performance in Li-ion batteries. However, their applicability in other battery chemistries have not been well explored. In this work, an AP-based cathode material, Li2FeSeO, was systematically studied for application in Na-ion batteries (NIBs). Delithiated Li0.8FeSeO was used as a precursor for preparing an Na-ion analog. The electrochemical characterization of Na-based AP cathode revealed a reversible galvanostatic cycling behavior with an initial capacity of 129 mA g-1 and a capacity retention of 57% after 200 cycles when cycled at a current density of 10 mA g-1. Up to 0.75 Na+ can be reversibly inserted into the AP framework. Synchrotron operando and ex situ X-ray studies revealed a working mechanism based on a dual redox behavior including both Fe and Se, with Se being the main redox actor. The (de)sodiation capacity below expected value is possibly attributed to the formation of a core-shell structure formed due to kinetic limitation of Na+ diffusion into bulk structure, thus preventing a full utilization of the available redox activity. These findings establish AP cathodes as viable candidates for NIBs and provide mechanistic insights that can guide their future structural optimization.
Keywords: Na‐ion batteries; X‐ray absorption spectroscopy; X‐ray diffraction; antiperovskite cathodes; operando characterization.
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