Microsomal cytochrome P-450 from neonatal pig testis. Purification and properties of A C21 steroid side-chain cleavage system (17 alpha-hydroxylase-C17,20 lyase)

J Biol Chem. 1981 Apr 25;256(8):3871-6.

Abstract

A cytochrome P-450 from neonatal pig testicular microsomes was purified to homogeneity as judged by electrophoresis on sodium dodecyl sulfate-polyacrylamide gels and by double diffusion on agar against antiserum raised in rabbits against the protein. The enzyme shows both 17 alpha-hydroxylase (Vmax = 4.6 nmol of product/min/nmol of P-450, Km = 1.5 microM) and C17,20 lyase (Vmax = 2.6 nmol of product/min/nmol of P-450, Km = 2.4 microM) activities. Both activities require NADPH and a flavoprotein P-450 reductase; microsomal P-450 reductase from pig and rat livers was used in these studies. The enzyme possesses a single subunit of molecular weight 59,000 +/- 1,000 as determined by electrophoresis on polyacrylamide with sodium dodecyl sulfate and by chromatography on sodium dodecyl sulfate-Sephadex. The enzyme is a glycoprotein and contains 8 nmol of heme/mg of protein and 40 nmol of phospholipid/mg of protein. All heme detected by pyridine hemochromogen is accounted for as P-450 by difference spectroscopy of the reduced P-450.carbon monoxide complex. This complex shows an absorbance maximum at 448 nm with no evidence of P-420. These studies raise the possibility that one microsomal protein (cytochrome P-450) may possess two enzymatic activities (hydroxylase and lyase).

Publication types

  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Aldehyde-Lyases / isolation & purification
  • Aldehyde-Lyases / metabolism*
  • Animals
  • Animals, Newborn
  • Cytochrome P-450 Enzyme System / isolation & purification
  • Cytochrome P-450 Enzyme System / metabolism*
  • Heme / analysis
  • Hydroxyprogesterones / isolation & purification
  • Hydroxyprogesterones / metabolism
  • Kinetics
  • Male
  • Microsomes / enzymology*
  • Multienzyme Complexes / isolation & purification
  • Multienzyme Complexes / metabolism
  • Spectrophotometry
  • Steroid 17-alpha-Hydroxylase / isolation & purification
  • Steroid 17-alpha-Hydroxylase / metabolism*
  • Steroid Hydroxylases / metabolism*
  • Swine
  • Testis / enzymology*

Substances

  • Hydroxyprogesterones
  • Multienzyme Complexes
  • Heme
  • Cytochrome P-450 Enzyme System
  • Steroid Hydroxylases
  • Steroid 17-alpha-Hydroxylase
  • Aldehyde-Lyases