Abstract
A test system is described, which allows the search for compounds interfering with human sex hormone-binding globulin (SHBG) even in complex plant extracts. The method has been evaluated and applied to Urtica dioica root extracts. The lignan secoisolariciresinol (5) as well as a mixture of isomeric (11 E)-9,10,13-trihydroxy-11-octadecenoic and (10 E)-9,12,13-trihydroxy-10-octadecenoic acids (3 and 4, resp.) were demonstrated to reduce binding activity of human SHBG. Methylation of the mixture of 3 and 4 increased its activity about 10-fold.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Dihydrotestosterone / metabolism
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Female
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Humans
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Hydroxy Acids / chemistry
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Hydroxy Acids / isolation & purification
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Hydroxy Acids / pharmacology*
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Kinetics
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Methylation
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Molecular Structure
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Oleic Acids / chemistry
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Oleic Acids / isolation & purification
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Oleic Acids / pharmacology*
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Plant Extracts / pharmacology*
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Plant Roots
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Plants, Medicinal*
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Pregnancy
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Pregnancy Trimester, Third
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Protein Binding
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Serum Albumin / isolation & purification
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Serum Albumin / metabolism
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Sex Hormone-Binding Globulin / antagonists & inhibitors*
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Sex Hormone-Binding Globulin / isolation & purification
Substances
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Hydroxy Acids
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Oleic Acids
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Plant Extracts
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Serum Albumin
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Sex Hormone-Binding Globulin
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Dihydrotestosterone
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9,10,13-trihydroxy-11-octadecenoic acid