Delboeuf's writings on psychophysics are little known nowadays. The object of this paper is to describe the psychological contributions of this eminent Belgian psychologist of the second half of the 19th century. A true pioneer of experimental psychology, his work on psychophysics began in 1865 at the University of Gand (Ghent) but was not published until 1873 and following years. His work in this area is characterised on the one hand by the adoption of a logarithmic law relating sensation strength to stimulus strength, but which differed from that of Fechner; and on the other hand by the utilisation of a psychophysical technique based on brightness contrast (now called the 'bisection method'). Even though, Delboeuf was classified by Fechner in his later writings as an opponent of his beliefs. Delboeuf was nevertheless one of his least-virulent critics and the only psychologist of that era to have adopted a logarithmic law. Delboeuf's work is not only of historic interest; his original ideas possess sufficient interest for present-day psychophysicists to reexamine them.