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Exceptionally High Proton and Lithium Cation Gas-Phase Basicity of the Anti-Diabetic Drug Metformin.
Raczyńska ED, Gal JF, Maria PC, Michalec P, Zalewski M. Raczyńska ED, et al. J Phys Chem A. 2017 Nov 16;121(45):8706-8718. doi: 10.1021/acs.jpca.7b09338. Epub 2017 Nov 2. J Phys Chem A. 2017. PMID: 29035049
At the density functional theory (DFT) level {essentially B3LYP/6-311+G(d,p)}, the most stable structures correspond to the conjugated, push-pull, system (NR(2))(NH(2))CN-C(NH)NH(2) (R = H, CH(3)), further stabilized by an internal hydrogen bond. The structural and energetic aspe …
At the density functional theory (DFT) level {essentially B3LYP/6-311+G(d,p)}, the most stable structures correspond to the conjugated, push …
[Distribution and elimination behavior of lithium in young and adult rats following acute administration of various inorganic cations and anions].
Kersten L, Bräunlich H. Kersten L, et al. Acta Biol Med Ger. 1982;41(4):365-75. Acta Biol Med Ger. 1982. PMID: 7124254 German.
The administrations of KCl or NH4Cl have no important consequences on lithium kinetics. Although the transport of lithium in kidney does not occur by the Na+K+-pump, renal and extrarenal interactions between sodium and lithium ions seem to exist. The expulsio …
The administrations of KCl or NH4Cl have no important consequences on lithium kinetics. Although the transport of lithium in k …