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Higher hydrates of lithium chloride, lithium bromide and lithium iodide.
Sohr J, Schmidt H, Voigt W. Sohr J, et al. Acta Crystallogr C Struct Chem. 2018 Feb 1;74(Pt 2):194-202. doi: 10.1107/S2053229618001183. Epub 2018 Jan 23. Acta Crystallogr C Struct Chem. 2018. PMID: 29400335
In this study, the crystal structures of the di- and trihydrates of lithium chloride, lithium bromide and lithium iodide, and the pentahydrates of lithium chloride and lithium bromide have been determined. In each hydrate, the lithium …
In this study, the crystal structures of the di- and trihydrates of lithium chloride, lithium bromide and lithium iodid …
Regulating Dynamic Evolution of Interfacial Electrolyte Configuration via Inert Cation Induced Anion Anchoring to Stabilize Lithium-Metal Anode.
Wang J, Li Y, Tu W, Zhang H, Yu X, Yang Y, Luo H, Zhao Q, Ru Y, Chen M, Hong Y, Ye J, Li JF, Liu N, Ouyang C, Wang H, Zou Y, Feng G, Qiao Y, Sun SG. Wang J, et al. Angew Chem Int Ed Engl. 2025 Oct 13;64(42):e202513839. doi: 10.1002/anie.202513839. Epub 2025 Aug 26. Angew Chem Int Ed Engl. 2025. PMID: 40856242
Interfacial stability in high-energy-density lithium metal batteries (LMBs) hinges on precise regulation of dynamic interfacial electrolyte configuration. ...
Interfacial stability in high-energy-density lithium metal batteries (LMBs) hinges on precise regulation of dynamic interfacial elect …
Coulombic self-ordering upon charging a large-capacity layered cathode material for rechargeable batteries.
Mortemard de Boisse B, Reynaud M, Ma J, Kikkawa J, Nishimura SI, Casas-Cabanas M, Delmas C, Okubo M, Yamada A. Mortemard de Boisse B, et al. Nat Commun. 2019 May 16;10(1):2185. doi: 10.1038/s41467-019-09409-1. Nat Commun. 2019. PMID: 31097700 Free PMC article.
Lithium- and sodium-rich layered transition-metal oxides have recently been attracting significant interest because of their large capacity achieved by additional oxygen-redox reactions. However, layered transition-metal oxides exhibit structural degradation such as cat …
Lithium- and sodium-rich layered transition-metal oxides have recently been attracting significant interest because of their large ca …
Dislocation and oxygen-release driven delithiation in Li2MnO3.
Nakayama K, Ishikawa R, Kobayashi S, Shibata N, Ikuhara Y. Nakayama K, et al. Nat Commun. 2020 Sep 8;11(1):4452. doi: 10.1038/s41467-020-18285-z. Nat Commun. 2020. PMID: 32901015 Free PMC article.
Lithium-excess layered cathode materials such as Li(2)MnO(3) have attracted much attention owing to their high energy densities. ...We elucidate that the delithiated regions have extensive amounts of irreversible defects such as oxygen-release and Mn/Li cation-mixin …
Lithium-excess layered cathode materials such as Li(2)MnO(3) have attracted much attention owing to their high energy densities. ...W …
Assessment of the Accuracy of DFT-Predicted Li+-Nucleic Acid Binding Energies.
Boychuk BTA, Rebecca Jeong YE, Wetmore SD. Boychuk BTA, et al. J Chem Theory Comput. 2021 Aug 10;17(8):5392-5408. doi: 10.1021/acs.jctc.1c00401. Epub 2021 Aug 2. J Chem Theory Comput. 2021. PMID: 34339194
Understanding how lithium interacts with complex biosystems is crucial for uncovering the roles of this alkali metal in biology and designing extraction techniques for battery production and environmental remediation. ...Nevertheless, only three functionals tested (B2-PLYP …
Understanding how lithium interacts with complex biosystems is crucial for uncovering the roles of this alkali metal in biology and d …
Silylanions: inversion barriers and NMR chemical shifts.
Flock M, Marschner C. Flock M, et al. Chemistry. 2002 Mar 1;8(5):1024-30. doi: 10.1002/1521-3765(20020301)8:5<1024::aid-chem1024>3.0.co;2-u. Chemistry. 2002. PMID: 11891888
The influence of counterions on these barriers is probed by addition of a lithium or potassium cation. In most cases, a decrease of the energy barriers with respect to the bare anions is observed. ...
The influence of counterions on these barriers is probed by addition of a lithium or potassium cation. In most cases, a decrea …
Heterovalent Cation Substitution to Enhance the Ionic Conductivity of Halide Electrolytes.
Luo X, Wu X, Xiang J, Cai D, Li M, Wang X, Xia X, Gu C, Tu J. Luo X, et al. ACS Appl Mater Interfaces. 2021 Oct 13;13(40):47610-47618. doi: 10.1021/acsami.1c13295. Epub 2021 Sep 28. ACS Appl Mater Interfaces. 2021. PMID: 34581559
Application of halide electrolytes including Li(3)InCl(6) in all-solid-state lithium-metal batteries is still challenging due to the instability with lithium metal and limited ionic conductivity compared with liquid electrolytes and some sulfides. ...As a result, th …
Application of halide electrolytes including Li(3)InCl(6) in all-solid-state lithium-metal batteries is still challenging due to the …
Study of LiCoO(2)/Li(7)La(3)Zr(2)O(12):Ta Interface Degradation in All-Solid-State Lithium Batteries.
Ihrig M, Finsterbusch M, Laptev AM, Tu CH, Tran NTT, Lin CA, Kuo LY, Ye R, Sohn YJ, Kaghazchi P, Lin SK, Fattakhova-Rohlfing D, Guillon O. Ihrig M, et al. ACS Appl Mater Interfaces. 2022 Mar 9;14(9):11288-11299. doi: 10.1021/acsami.1c22246. Epub 2022 Feb 28. ACS Appl Mater Interfaces. 2022. PMID: 35226453
Excluding the possibility of mechanical failure due to crack formation between the LiCoO(2)/LLZO interface, a detailed investigation of the LiCoO(2)/LLZO interface before and after cycling clearly demonstrated cation diffusion between LiCoO(2) and the LLZO. This electroche …
Excluding the possibility of mechanical failure due to crack formation between the LiCoO(2)/LLZO interface, a detailed investigation of the …
Near-Saturated Coordinated Cations in Oxyhalide Superionic Conductors Boost High-Rate All-Solid-State Batteries.
Qian L, Tu S, Wang Y, Yang X, Ye C, Qiao SZ. Qian L, et al. J Am Chem Soc. 2025 Jul 2;147(26):23170-23179. doi: 10.1021/jacs.5c07052. Epub 2025 Jun 16. J Am Chem Soc. 2025. PMID: 40524353
Based on this correlation, near-saturated coordinated cation (NSCC)-incorporated Li(1.5)Zr(0.5)M(0.5)Cl(5.0)O(0.5) SEs (M = Nb or Ta, denoted as Nb- or Ta-LZCO) are developed with abundant vacancy concentrations and weakened Li-Cl interaction, thereby significantly enhanci …
Based on this correlation, near-saturated coordinated cation (NSCC)-incorporated Li(1.5)Zr(0.5)M(0.5)Cl(5.0)O(0.5) SEs (M = Nb or Ta, …
Influencing the froth flotation of LiAlO2 and melilite solid solution with ionic liquids.
Qiu H, Degenhardt C, Feuge N, Goldmann D, Wilhelm R. Qiu H, et al. RSC Adv. 2022 Oct 17;12(45):29562-29568. doi: 10.1039/d2ra02922g. eCollection 2022 Oct 11. RSC Adv. 2022. PMID: 36320758 Free PMC article.
In the present work experiments for single mineral flotation against LiAlO(2) and melilite s.s. were carried out for seven ionic liquids (ILs). From these, IL-1 with an imidazolium cation and a bromide anion and IL-7 with a pyridinium cation and a bromide anion were …
In the present work experiments for single mineral flotation against LiAlO(2) and melilite s.s. were carried out for seven ionic liquids (IL …
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