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196 results
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Page 1
Saturn Systems.
U Rehman H, McKee NA, McKee ML. U Rehman H, et al. J Comput Chem. 2016 Jan 15;37(2):194-209. doi: 10.1002/jcc.23979. Epub 2015 Jun 19. J Comput Chem. 2016. PMID: 26096724
Binding enthalpies and binding free energies in dichloromethane and toluene have been computed. The effect of an encapsulated lithium cation is accessed by comparing C60 @(C6 H4 )10 and [Li@C60 @(C6 H4 )10 ](+). The [Li@C60 ](+) cation is a much better accept …
Binding enthalpies and binding free energies in dichloromethane and toluene have been computed. The effect of an encapsulated lithium …
Innovative Approaches to Li-Argyrodite Solid Electrolytes for All-Solid-State Lithium Batteries.
Zhou L, Minafra N, Zeier WG, Nazar LF. Zhou L, et al. Acc Chem Res. 2021 Jun 15;54(12):2717-2728. doi: 10.1021/acs.accounts.0c00874. Epub 2021 May 25. Acc Chem Res. 2021. PMID: 34032414
These factors are all vital for commercial applications.In this Account, we afford an overview of our recent development of several argyrodite superionic conductors, including Li(6.6)Si(0.6)Sb(0.5)S(5)I (24 mS.cm(-1)), Li(6.6)Ge(0.6)P(0.4)S(5)I (18 mS.cm(-1)), and Li(5.5)PS(4.5)C …
These factors are all vital for commercial applications.In this Account, we afford an overview of our recent development of several argyrodi …
"Naked" Lithium Cation: Strongly Activated Metal Cations Facilitated by Carborane Anions.
Kitazawa Y, Takita R, Yoshida K, Muranaka A, Matsubara S, Uchiyama M. Kitazawa Y, et al. J Org Chem. 2017 Feb 17;82(4):1931-1935. doi: 10.1021/acs.joc.6b02677. Epub 2017 Jan 27. J Org Chem. 2017. PMID: 28103032
Experimental and spectroscopic studies revealed unprecedented reactivity of a "naked" lithium cation with very weakly coordinating anions, including carborane anions. ...Chemical robustness of the counteranion also plays an important role in the chemistry of the str …
Experimental and spectroscopic studies revealed unprecedented reactivity of a "naked" lithium cation with very weakly coordina …
The Bis(η6 -benzene)lithium Cation: A Fundamental Main-Group Organometallic Species.
Jie X, Li J, Daniliuc CG, Wübker AL, Hansen MR, Eckert H, Mück-Lichtenfeld C, Kehr G, Erker G. Jie X, et al. Angew Chem Int Ed Engl. 2021 Oct 11;60(42):22879-22884. doi: 10.1002/anie.202108376. Epub 2021 Sep 12. Angew Chem Int Ed Engl. 2021. PMID: 34363618
The synthesis and characterization of the bis(eta(6) -benzene)lithium cation, the benzene metallocene of the lightest metal, is reported. ...Subsequent crystallization from benzene gave the [bis(eta(6) -benzene)Li](+) cation with the [{FmesB(-CC-Fmxyl)(3) }(2 …
The synthesis and characterization of the bis(eta(6) -benzene)lithium cation, the benzene metallocene of the lightest metal, i …
Lithium-Cation Conductivity of Solid Solutions in Li6-xZr2-xAxO7 (A = Nb, Ta) Systems.
Shekhtman GS, Kalashnova AV, Antonov BD. Shekhtman GS, et al. Materials (Basel). 2021 Nov 16;14(22):6904. doi: 10.3390/ma14226904. Materials (Basel). 2021. PMID: 34832306 Free PMC article.
Li(5.8)Zr(1.8)Nb(Ta)(0.2)O(7) solid solutions have a higher lithium-cation conductivity at 300 C compared to solid electrolytes based on other lithium zirconates due the "open" structure of monoclinic Li(6)Zr(2)O(7) and a high solubility of the doping cations …
Li(5.8)Zr(1.8)Nb(Ta)(0.2)O(7) solid solutions have a higher lithium-cation conductivity at 300 C compared to solid electrolyte …
Ionic-Liquid-Based Polymer Electrolytes for Battery Applications.
Osada I, de Vries H, Scrosati B, Passerini S. Osada I, et al. Angew Chem Int Ed Engl. 2016 Jan 11;55(2):500-13. doi: 10.1002/anie.201504971. Epub 2015 Nov 19. Angew Chem Int Ed Engl. 2016. PMID: 26783056 Review.
The advent of solid-state polymer electrolytes for application in lithium batteries took place more than four decades ago when the ability of polyethylene oxide (PEO) to dissolve suitable lithium salts was demonstrated. ...This Review focuses on ternary polymer elec …
The advent of solid-state polymer electrolytes for application in lithium batteries took place more than four decades ago when the ab …
Modulation of Gas-Phase Lithium Cation Basicities by Microsolvation.
Koszinowski K, Auth T. Koszinowski K, et al. J Am Soc Mass Spectrom. 2019 Oct;30(10):1857-1866. doi: 10.1007/s13361-019-02312-5. Epub 2019 Sep 9. J Am Soc Mass Spectrom. 2019. PMID: 31502224
In contrast to the extensive knowledge of lithium cation affinities and basicities, the thermochemistry of microsolvated lithium cations is much less explored. ...This finding shows that microsolvation of Li(+) can result in specific effects, which are not re …
In contrast to the extensive knowledge of lithium cation affinities and basicities, the thermochemistry of microsolvated li …
Electrophilic Iron Catalyst Paired with a Lithium Cation Enables Selective Functionalization of Non-Activated Aliphatic C-H Bonds via Metallocarbene Intermediates.
Hernán-Gómez A, Rodríguez M, Parella T, Costas M. Hernán-Gómez A, et al. Angew Chem Int Ed Engl. 2019 Sep 23;58(39):13904-13911. doi: 10.1002/anie.201905986. Epub 2019 Aug 21. Angew Chem Int Ed Engl. 2019. PMID: 31338944 Review.
Reactions occur at 25 C via alpha-alkyl-metallocarbene intermediates, and with activity/selectivity levels similar to those of rhodium carboxylate catalysts. Mechanistic investigations reveal a crucial role of the lithium cation in the rate-determining formation of …
Reactions occur at 25 C via alpha-alkyl-metallocarbene intermediates, and with activity/selectivity levels similar to those of rhodium carbo …
Structure of [60]fullerene with a mobile lithium cation inside.
Aoyagi S, Miwa K, Ueno H, Okada H, Matsuo Y, Kokubo K. Aoyagi S, et al. R Soc Open Sci. 2018 Jul 18;5(7):180337. doi: 10.1098/rsos.180337. eCollection 2018 Jul. R Soc Open Sci. 2018. PMID: 30109088 Free PMC article.
The structure of crystalline [60]fullerene with a lithium cation inside (Li(+)@C(60)) was determined by synchrotron radiation X-ray diffraction measurements to understand the electrostatic and thermal properties of the encapsulated Li(+) cation. ...
The structure of crystalline [60]fullerene with a lithium cation inside (Li(+)@C(60)) was determined by synchrotron radiation …
196 results