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Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-Carbonylation of Sulfonimidamides.
J Am Chem Soc. 2023 Sep 27;145(38):20959-20967. doi: 10.1021/jacs.3c06674. Epub 2023 Sep 1.
J Am Chem Soc. 2023.
PMID: 37656964
Data Science Enables the Development of a New Class of Chiral Phosphoric Acid Catalysts.
Liles JP, Rouget-Virbel C, Wahlman JLH, Rahimoff R, Crawford JM, Medlin A, O'Connor V, Li J, Roytman VA, Toste FD, Sigman MS.
Liles JP, et al. Among authors: roytman va.
Chem. 2023 Jun 8;9(6):1518-1537. doi: 10.1016/j.chempr.2023.02.020. Epub 2023 Mar 24.
Chem. 2023.
PMID: 37519827
Free PMC article.
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Development of high-voltage bipolar redox-active organic molecules through the electronic coupling of catholyte and anolyte structures.
Tracy JS, Horst ES, Roytman VA, Toste FD.
Tracy JS, et al. Among authors: roytman va.
Chem Sci. 2022 Sep 1;13(36):10806-10814. doi: 10.1039/d2sc03450f. eCollection 2022 Sep 21.
Chem Sci. 2022.
PMID: 36320695
Free PMC article.
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Solvation Dynamics and the Nature of Reaction Barriers and Ion-Pair Intermediates in Carbocation Reactions.
Roytman VA, Singleton DA.
Roytman VA, et al.
J Am Chem Soc. 2020 Jul 22;142(29):12865-12877. doi: 10.1021/jacs.0c06295. Epub 2020 Jul 12.
J Am Chem Soc. 2020.
PMID: 32578428
Free PMC article.
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Bond Memory in Dynamically Determined Stereoselectivity.
Roytman VA, Jin S, Nguyen VT, Nguyen VD, Haug GC, Larionov OV, Singleton DA.
Roytman VA, et al.
J Am Chem Soc. 2020 Jan 8;142(1):85-88. doi: 10.1021/jacs.9b12227. Epub 2019 Dec 20.
J Am Chem Soc. 2020.
PMID: 31852185
Free PMC article.
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Comment on "Activation of methane to CH3 +: A selective industrial route to methanesulfonic acid".
Roytman VA, Singleton DA.
Roytman VA, et al.
Science. 2019 May 10;364(6440):eaax7083. doi: 10.1126/science.aax7083.
Science. 2019.
PMID: 31073043
Free PMC article.
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13 C Kinetic Isotope Effects as a Quantitative Probe To Distinguish between Enol and Enamine Mechanisms in Aminocatalysis.
Roytman VA, Karugu RW, Hong Y, Hirschi JS, Vetticatt MJ.
Roytman VA, et al.
Chemistry. 2018 Jun 7;24(32):8098-8102. doi: 10.1002/chem.201801748. Epub 2018 May 14.
Chemistry. 2018.
PMID: 29654709
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