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Impact of the equatorial coordination sphere on the rate of reduction, lipophilicity and cytotoxic activity of platinum(IV) complexes.
Höfer D, Varbanov HP, Hejl M, Jakupec MA, Roller A, Galanski MS, Keppler BK. Höfer D, et al. J Inorg Biochem. 2017 Sep;174:119-129. doi: 10.1016/j.jinorgbio.2017.06.005. Epub 2017 Jun 16. J Inorg Biochem. 2017. PMID: 28666155
The impact of the equatorial coordination sphere on the reduction behavior (i.e. rate of reduction) of platinum(IV) complexes with axial carboxylato ligands was studied. ...For this purpose, a series of platinum(IV) complexes featuring axial carboxylato ligands (succinic a …
The impact of the equatorial coordination sphere on the reduction behavior (i.e. rate of reduction) of platinum(IV) complexes with ax …
Novel endothall-containing platinum(IV) complexes: synthesis, characterization, and cytotoxic activity.
Reithofer MR, Valiahdi SM, Galanski M, Jakupec MA, Arion VB, Keppler BK. Reithofer MR, et al. Chem Biodivers. 2008 Oct;5(10):2160-2170. doi: 10.1002/cbdv.200890197. Chem Biodivers. 2008. PMID: 18972539
Cytotoxicity of the complexes was studied in seven human cancer cell lines representing five tumor entities, i.e., ovarian carcinoma (CH1, SK-OV-3), cervical carcinoma (HeLa), colon carcinoma (SW480, HCT-116), osteosarcoma (U-2 OS), and hepatocellular carcinoma (Hep G2) by …
Cytotoxicity of the complexes was studied in seven human cancer cell lines representing five tumor entities, i.e., ovarian carcinoma …
An electrochemical study of antineoplastic gallium, iron and ruthenium complexes with redox noninnocent alpha-N-heterocyclic chalcogensemicarbazones.
Kowol CR, Reisner E, Chiorescu I, Arion VB, Galanski MS, Deubel DV, Keppler BK. Kowol CR, et al. Inorg Chem. 2008 Dec 1;47(23):11032-47. doi: 10.1021/ic8013249. Inorg Chem. 2008. PMID: 18973290
The electrochemical properties of a series of alpha-N-heterocyclic chalcogensemicarbazones (HL), namely, thiosemicarbazones, selenosemicarbazones, and semicarbazones, and their gallium(III), iron(III), and ruthenium(III) complexes with the general formula [ML(2)][Y] (M = G …
The electrochemical properties of a series of alpha-N-heterocyclic chalcogensemicarbazones (HL), namely, thiosemicarbazones, selenosemicarba …
Metal-based paullones as putative CDK inhibitors for antitumor chemotherapy.
Schmid WF, John RO, Mühlgassner G, Heffeter P, Jakupec MA, Galanski MS, Berger W, Arion VB, Keppler BK. Schmid WF, et al. J Med Chem. 2007 Dec 13;50(25):6343-55. doi: 10.1021/jm701042w. Epub 2007 Nov 13. J Med Chem. 2007. PMID: 17997519
They were found to form organometallic complexes of the general formula [M (II)Cl(eta (6)- p-cymene)L]Cl ( 1- 4, L = L (1) - L (4) ; a, M = Ru; b, M = Os). The complexes were characterized by X-ray crystallography, one- and two-dimensional NMR spectroscopy an …
They were found to form organometallic complexes of the general formula [M (II)Cl(eta (6)- p-cymene)L]Cl ( 1- 4, L = L (1) - L (4) ; …
Amidines derived from Pt(IV)-mediated nitrile-amino alcohol coupling and their Zn(II)-catalyzed conversion into oxazolines.
Makarycheva-Mikhailova AV, Kukushkin VY, Nazarov AA, Garnovskii DA, Pombeiro AJ, Haukka M, Keppler BK, Galanski MS. Makarycheva-Mikhailova AV, et al. Inorg Chem. 2003 Apr 21;42(8):2805-13. doi: 10.1021/ic034070t. Inorg Chem. 2003. PMID: 12691592
NOESY spectroscopy indicates that the liberated amidines retained the same configuration relative to the C=N double bond, i.e., syn-(H,Et)-NH=C(Et)NHCHRCH(2)OH. The liberated hydroxo-functionalized amidines 8-10 were converted into oxazolines (11-13) in the presence of a c …
NOESY spectroscopy indicates that the liberated amidines retained the same configuration relative to the C=N double bond, i.e., syn-( …