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2020 1
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Page 1
Secondary-Rim γ-Cyclodextrin Functionalization to Conjugate with C60 : Improved Efficacy as a Photosensitizer.
Zhu X, Quaranta A, Bensasson RV, Sollogoub M, Zhang Y. Zhu X, et al. Chemistry. 2017 Jul 18;23(40):9462-9466. doi: 10.1002/chem.201700782. Epub 2017 Jun 29. Chemistry. 2017. PMID: 28548683
The water solubility of 0.12 m (550 mg mL(-1) ) is 150 times higher than that of the native γ-CD/C(60) complex. Its singlet oxygen ((1) O(2) ) quantum yield is 0.39, an increase of one to two orders of magnitude compared to that of α(β)CD-C(60) conjugates....
The water solubility of 0.12 m (550 mg mL(-1) ) is 150 times higher than that of the native γ-CD/C(60) complex. Its singlet oxygen (( …
Orchestrating Communications in a Three-Type Chirality Totem: Remote Control of the Chiroptical Response of a Möbius Aromatic System.
Benchouaia R, Cissé N, Boitrel B, Sollogoub M, Le Gac S, Ménand M. Benchouaia R, et al. J Am Chem Soc. 2019 Jul 24;141(29):11583-11593. doi: 10.1021/jacs.9b04074. Epub 2019 Jul 9. J Am Chem Soc. 2019. PMID: 31251054 Free article.
Whereas their flexibility needs to be controlled to get P/M twist enantioselectivity, it could be of great interest to sustain dynamic chirality transfer. ...
Whereas their flexibility needs to be controlled to get P/M twist enantioselectivity, it could be of great interest to sustain dynami …
Stable DNA triple helix formation using oligonucleotides containing 2'-aminoethoxy,5-propargylamino-U.
Sollogoub M, Darby RA, Cuenoud B, Brown T, Fox KR. Sollogoub M, et al. Biochemistry. 2002 Jun 11;41(23):7224-31. doi: 10.1021/bi020164n. Biochemistry. 2002. PMID: 12044153
UV- and fluorescence melting studies with intramolecular triplexes confirmed that the bis-modified base produces a much greater increase in T(m) than either modification alone....
UV- and fluorescence melting studies with intramolecular triplexes confirmed that the bis-modified base produces a much greater increase in …
An Epoxide Intermediate in Glycosidase Catalysis.
Sobala LF, Speciale G, Zhu S, Raich L, Sannikova N, Thompson AJ, Hakki Z, Lu D, Shamsi Kazem Abadi S, Lewis AR, Rojas-Cervellera V, Bernardo-Seisdedos G, Zhang Y, Millet O, Jiménez-Barbero J, Bennet AJ, Sollogoub M, Rovira C, Davies GJ, Williams SJ. Sobala LF, et al. ACS Cent Sci. 2020 May 27;6(5):760-770. doi: 10.1021/acscentsci.0c00111. Epub 2020 Apr 16. ACS Cent Sci. 2020. PMID: 32490192 Free PMC article.
Kinetic isotope effects (k (cat)/K (M)) for anomeric-(2)H and anomeric-(13)C support an oxocarbenium ion-like transition state, and that for C2-(18)O (1.052 ± 0.006) directly implicates nucleophilic participation by the C2-hydroxyl. ...
Kinetic isotope effects (k (cat)/K (M)) for anomeric-(2)H and anomeric-(13)C support an oxocarbenium ion-like transition state, and t …
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