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Showing results for A. K. durban
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Oxyhalogen-Sulfur Chemistry: Kinetics and Mechanism of Oxidation of 1,3-Dimethylthiourea by Acidic Bromate.
Olagunju O, Simoyi RH. Olagunju O, et al. J Phys Chem A. 2017 Aug 31;121(34):6366-6376. doi: 10.1021/acs.jpca.7b07587. Epub 2017 Aug 21. J Phys Chem A. 2017. PMID: 28793188
The direct reaction of aqueous bromine with DMTU, with a bimolecular rate constant of k = (1.95 0.15) 10(5) M(-1) s(-1), is much faster than reactions that form bromine such that formation of bromine indicates complete consumption of DMTU. ...
The direct reaction of aqueous bromine with DMTU, with a bimolecular rate constant of k = (1.95 0.15) 10(5) M(-1) s(-1), is much fast …
Kinetics of inactivation of Pseudomonas aeruginosa in aqueous solutions by ozone aeration.
Zuma FN, Lin J, Jonnalagadda SB. Zuma FN, et al. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2009 Aug;44(10):929-35. doi: 10.1080/10934520902996807. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2009. PMID: 19827485
The microbial inactivation kinetics followed pseudo-first-order kinetics under excess concentration conditions of ozone. With over all second-order constant, k = (4.02 +/- 0.20) x 10(4) M(-1) min(-1), the reaction rate had first-order dependence both on the microbial count …
The microbial inactivation kinetics followed pseudo-first-order kinetics under excess concentration conditions of ozone. With over all secon …
Kinetics and mechanism of the oxidation of amaranth with hypochlorite.
Nadupalli S, Koorbanally N, Jonnalagadda SB. Nadupalli S, et al. J Phys Chem A. 2011 Jul 14;115(27):7948-54. doi: 10.1021/jp202812f. Epub 2011 Jun 17. J Phys Chem A. 2011. PMID: 21648412
The energy parameters were E(a) = 33.7 kJ mol(-1), deltaH() = 31.2 kJ mol(-1) and deltaS() = -190.6 J K(-1) mol(-1) for the OCl(-) ion-driven oxidation, and E(a) = 26.9 kJ mol(-1), deltaH() = 24.3 kJ mol(-1) and deltaS() = -222.8 J K(-1) mol(-1) for the reaction wit …
The energy parameters were E(a) = 33.7 kJ mol(-1), deltaH() = 31.2 kJ mol(-1) and deltaS() = -190.6 J K(-1) mol(-1) for the OCl(-) io …
Impact of HLA-driven HIV adaptation on virulence in populations of high HIV seroprevalence.
Payne R, Muenchhoff M, Mann J, Roberts HE, Matthews P, Adland E, Hempenstall A, Huang KH, Brockman M, Brumme Z, Sinclair M, Miura T, Frater J, Essex M, Shapiro R, Walker BD, Ndung'u T, McLean AR, Carlson JM, Goulder PJ. Payne R, et al. Proc Natl Acad Sci U S A. 2014 Dec 16;111(50):E5393-400. doi: 10.1073/pnas.1413339111. Epub 2014 Dec 1. Proc Natl Acad Sci U S A. 2014. PMID: 25453107 Free PMC article.
Investigation of binding interactions between BSA and [EPMpyr][Sal] through spectroscopy studies, thermophysical and thermodynamic properties.
Arumugam V, Rajamanikandan R, Ilanchelian M, Moodley KG, Redhi GG. Arumugam V, et al. Spectrochim Acta A Mol Biomol Spectrosc. 2019 Mar 5;210:299-307. doi: 10.1016/j.saa.2018.11.024. Epub 2018 Nov 14. Spectrochim Acta A Mol Biomol Spectrosc. 2019. PMID: 30471538
Thermodynamic data (excess molar volume (V(m)(E)), isentropic compressibility (k(s)), deviation in isentropic compressibility (k(s)) and intermolecular free length (L(f))) showed that there were stronger interaction between IL and BSA at higher temperature. ...
Thermodynamic data (excess molar volume (V(m)(E)), isentropic compressibility (k(s)), deviation in isentropic compressibility (k
Chlorine dioxide-facilitated oxidation of the azo dye amaranth.
Nadupalli S, Koorbanally N, Jonnalagadda SB. Nadupalli S, et al. J Phys Chem A. 2011 Oct 27;115(42):11682-8. doi: 10.1021/jp206175s. Epub 2011 Oct 4. J Phys Chem A. 2011. PMID: 21923171
The energy and entropy of activation values for the reaction were 50.0 kJ mol(-1) and -658.7 J K(-1) mol(-1), respectively. A probable reaction mechanism was elucidated and was validated by simulations....
The energy and entropy of activation values for the reaction were 50.0 kJ mol(-1) and -658.7 J K(-1) mol(-1), respectively. A probabl …
Thermodynamic spectral and kinetic analysis of the removal of Cu(II) from aqueous solution by sodium carbonate treated rice husk.
Acharya J, Kumar U, Meikap BC. Acharya J, et al. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2019;54(8):801-809. doi: 10.1080/10934529.2019.1596699. Epub 2019 Apr 10. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2019. PMID: 30966870
The values of deltaH and deltaS for Cu(II) adsorption were calculated as 14.37 kJ mol(-1) and 70.92 J K(-1) mol(-1), respectively. The activation energy for the adsorption of Cu(II) was found to be 9 kJ mol(-1) which is a characteristic for diffusion limited processes....
The values of deltaH and deltaS for Cu(II) adsorption were calculated as 14.37 kJ mol(-1) and 70.92 J K(-1) mol(-1), respectively. Th …
Treatment of petroleum refinery sludge by petroleum degrading bacterium Stenotrophomonas pavanii IRB19 as an efficient novel technology.
Behera ID, Basak G, Kumar RR, Sen R, Meikap BC. Behera ID, et al. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2021;56(2):226-239. doi: 10.1080/10934529.2020.1866924. Epub 2020 Dec 30. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2021. PMID: 33378252
The TPH degradation best fitted for the Gompertz model and followed the first-order kinetics having the rate constant (k) and half-life period (t (1/2)) of 0.036 d(-1) and 19 d, respectively. Results of this study verified the suitability of the novel strain IRB19 for the …
The TPH degradation best fitted for the Gompertz model and followed the first-order kinetics having the rate constant (k) and half-li …