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Steric effects on the primary isotope dependence of secondary kinetic isotope effects in hydride transfer reactions in solution: caused by the isotopically different tunneling ready state conformations?
Maharjan B, Raghibi Boroujeni M, Lefton J, White OR, Razzaghi M, Hammann BA, Derakhshani-Molayousefi M, Eilers JE, Lu Y. Maharjan B, et al. Among authors: derakhshani molayousefi m. J Am Chem Soc. 2015 May 27;137(20):6653-61. doi: 10.1021/jacs.5b03085. Epub 2015 May 15. J Am Chem Soc. 2015. PMID: 25941865